Consider the reaction: CO(g) + H2O(g) ⇌ CO2(g) + H2(g) Kc = 102 at 500 K. If a reaction mixture initially contains 0.110 M CO and 0.110 M H2O, what will the equilibrium concentration of each of the reactants and products be?

Name: Chemistry: A Molecular Approach
Author: Tro
ISBN: 9780137832217

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Identify the initial concentrations of the reactants: [CO] = 0.110 M and [H2O] = 0.110 M. The initial concentrations of the products [CO2] and [H2] are 0 M.

Set up an ICE (Initial, Change, Equilibrium) table to track the changes in concentrations as the system reaches equilibrium. Let x be the change in concentration for CO and H2O as they react.

Write the expression for the equilibrium constant Kc: Kc = ([CO2][H2])/([CO][H2O]).

Substitute the equilibrium concentrations from the ICE table into the Kc expression: Kc = ((x)(x))/((0.110-x)(0.110-x)).

Solve the equation for x using the given Kc value (102) to find the equilibrium concentrations of all species.

주요 개념

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Chemical Equilibrium

Chemical equilibrium occurs when the rates of the forward and reverse reactions are equal, resulting in constant concentrations of reactants and products. In this state, the system is dynamic, meaning that reactions continue to occur, but there is no net change in concentration. Understanding this concept is crucial for analyzing how concentrations shift in response to changes in conditions.

Equilibrium Constant (Kc)

The equilibrium constant (Kc) is a numerical value that expresses the ratio of the concentrations of products to reactants at equilibrium, each raised to the power of their coefficients in the balanced equation. For the given reaction, Kc = [CO2][H2]/[CO][H2O]. This constant provides insight into the position of equilibrium and helps predict the concentrations of species at equilibrium based on initial concentrations.

ICE Table (Initial, Change, Equilibrium)

An ICE table is a tool used to organize the initial concentrations, the changes in concentrations as the reaction proceeds, and the equilibrium concentrations of reactants and products. By setting up an ICE table, one can systematically determine how the initial concentrations of CO and H2O will change to reach equilibrium, allowing for the calculation of equilibrium concentrations using the Kc value.