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Ch.16 - Chemical Equilibrium
Tro - Chemistry: A Molecular Approach 6th Edition
Tro6th EditionChemistry: A Molecular ApproachISBN: 9780137832217당신이 사용하는 게 아니라요?교과서 변경
16장, 문제 73

This reaction is endothermic. C(s) + CO2(g) ⇌ 2 CO(g) Predict the effect (shift right, shift left, or no effect) of increasing and decreasing the reaction temperature. How does the value of the equilibrium constant depend on temperature?

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Identify the type of reaction: The given reaction is endothermic, which means it absorbs heat. In the reaction equation, C(s) + CO2(g) ⇌ 2 CO(g), heat can be considered as a reactant.
Apply Le Chatelier's Principle: According to Le Chatelier's Principle, if a system at equilibrium is subjected to a change, the system will adjust itself to counteract that change and restore a new equilibrium.
Predict the effect of increasing temperature: Since the reaction is endothermic, increasing the temperature adds more heat to the system. This is akin to increasing the concentration of a reactant in a chemical reaction. Therefore, the system will shift to the right to consume the added heat, favoring the formation of more products (CO(g)).
Predict the effect of decreasing temperature: Decreasing the temperature removes heat from the system, similar to decreasing the concentration of a reactant. Thus, the system will shift to the left, favoring the formation of more reactants (C(s) and CO2(g)).
Understand the effect on the equilibrium constant (K): The equilibrium constant, K, for an endothermic reaction increases with an increase in temperature and decreases with a decrease in temperature. This is because K is directly related to the extent of product formation, which is favored by an increase in temperature in endothermic reactions.

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주요 개념

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Le Chatelier's Principle

Le Chatelier's Principle states that if a dynamic equilibrium is disturbed by changing the conditions, the system will adjust to counteract the change and restore a new equilibrium. In the context of temperature changes, increasing the temperature of an endothermic reaction will shift the equilibrium to the right, favoring the formation of products, while decreasing the temperature will shift it to the left, favoring the reactants.
추천 영상:
가이드 코스
07:32
Le Chatelier's Principle

Endothermic Reactions

Endothermic reactions absorb heat from their surroundings, resulting in a decrease in temperature of the environment. In the given reaction, the conversion of solid carbon and carbon dioxide gas into carbon monoxide gas requires heat input, which is why increasing the temperature will favor the production of CO, while decreasing it will hinder the reaction.
추천 영상:
가이드 코스
02:30
Endothermic & Exothermic Reactions

Equilibrium Constant (K)

The equilibrium constant (K) quantifies the ratio of the concentrations of products to reactants at equilibrium for a given reaction at a specific temperature. For endothermic reactions, increasing the temperature generally increases the value of K, indicating a greater concentration of products at equilibrium, while decreasing the temperature typically lowers K, favoring reactants.
추천 영상:
가이드 코스
01:14
Equilibrium Constant K
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