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Ch.15 Lipids
Timberlake - Chemistry: An Introduction to General, Organic, and Biological Chemistry 14th Edition
Timberlake14th EditionChemistry: An Introduction to General, Organic, and Biological ChemistryISBN: 9781292472249당신이 사용하는 게 아니라요?교과서 변경
15장, 문제 30a

Identify each of the following processes as hydrogenation, hydrolysis, or saponification and give the products:
a. the reaction of corn oil and hydrogen (H2) with a nickel catalyst

검증된 단계별 안내
1
Step 1: Recognize the type of reaction described in the problem. The reaction involves corn oil (a triglyceride) and hydrogen (H₂) in the presence of a nickel catalyst. This setup is characteristic of a hydrogenation reaction.
Step 2: Understand the process of hydrogenation. In hydrogenation, hydrogen (H₂) is added to the double bonds of unsaturated fatty acids in the triglyceride, converting them into single bonds. This process reduces the degree of unsaturation in the fatty acids.
Step 3: Identify the structural change in the triglyceride. The double bonds in the unsaturated fatty acids of corn oil are replaced with single bonds, resulting in the formation of saturated fatty acids.
Step 4: Predict the product of the reaction. The product of the hydrogenation of corn oil is a triglyceride with more saturated fatty acids, which is typically a solid or semi-solid fat at room temperature.
Step 5: Summarize the reaction. The process is hydrogenation, and the product is a more saturated form of the triglyceride (corn oil), often referred to as partially or fully hydrogenated oil.

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주요 개념

질문에 올바르게 답하기 위해 반드시 이해해야 하는 핵심 개념들은 다음과 같습니다.

Hydrogenation

Hydrogenation is a chemical reaction that involves the addition of hydrogen (H₂) to unsaturated organic compounds, typically alkenes or alkynes, to convert them into saturated compounds. This process is commonly used in the food industry to convert liquid vegetable oils into solid or semi-solid fats, improving shelf life and texture. In the context of the question, the reaction of corn oil with hydrogen in the presence of a nickel catalyst exemplifies hydrogenation, resulting in the formation of saturated fats.
추천 영상:
가이드 코스
1:22
Hydrogenation Reactions Concept 1

Corn Oil

Corn oil is a type of vegetable oil extracted from the germ of corn (maize). It is primarily composed of polyunsaturated fatty acids, making it liquid at room temperature. When corn oil undergoes hydrogenation, its unsaturated fatty acids are converted into saturated fatty acids, which alters its physical properties, such as melting point and stability. Understanding the composition of corn oil is essential for predicting the outcomes of its hydrogenation.
추천 영상:
가이드 코스
04:22
Rutherford Gold Foil Oil Experiment

Nickel Catalyst

A nickel catalyst is a substance that accelerates the rate of a chemical reaction without being consumed in the process. In hydrogenation reactions, nickel is commonly used due to its effectiveness in facilitating the addition of hydrogen to unsaturated bonds. The presence of a nickel catalyst in the reaction between corn oil and hydrogen is crucial, as it lowers the activation energy required for the reaction, allowing it to proceed more efficiently and at lower temperatures.
추천 영상:
가이드 코스
1:57
Reduction of Aldehydes and Ketones Concept 2