An aqueous solution of a cation (represented as blue spheres in the diagram) is allowed to mix with a solution of an anion (represented as green spheres) and the following result is obtained: Which combinations of cation and anion, chosen from the following lists, are compatible with the observed results? Explain.
Cations: Na+, Ca2+, Ag+, Ni2+
Anions: Cl−, CO2−3, CrO2−4, NO−3
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1
Observe the image: The green spheres represent anions and the red spheres represent cations. After mixing, a solid forms at the bottom, indicating a precipitate.
Identify the possible cation-anion combinations that form a precipitate. Use solubility rules to determine which combinations are insoluble in water.
Consider the cations: Na^+, Ca^{2+}, Ag^+, Ni^{2+}. Na^+ typically forms soluble compounds, so it is unlikely to form a precipitate.
Consider the anions: Cl^−, CO_3^{2−}, CrO_4^{2−}, NO_3^−. NO_3^− typically forms soluble compounds, so it is unlikely to form a precipitate.
Based on solubility rules, Ag^+ with Cl^− forms AgCl, a common precipitate. Similarly, Ca^{2+} with CO_3^{2−} forms CaCO_3, another common precipitate.
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주요 개념
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Ionic Compounds
Ionic compounds are formed when cations (positively charged ions) and anions (negatively charged ions) combine due to electrostatic attraction. The strength of this attraction depends on the charges of the ions and their sizes. In the context of the question, understanding how different cations and anions interact is crucial for predicting the formation of a stable compound and the resulting layered solution.
Solubility rules are guidelines that help predict whether an ionic compound will dissolve in water. Certain combinations of cations and anions are known to be soluble or insoluble based on these rules. For example, compounds containing Na+ or NO3− are generally soluble, while others may form precipitates. This concept is essential for determining which combinations of ions will lead to the observed results in the mixing process.
Precipitation reactions occur when two soluble ionic compounds react in solution to form an insoluble compound, which then separates from the solution as a solid. This process is indicated by the formation of layers in the diagram, suggesting that some ions may not be compatible and thus precipitate out. Understanding precipitation is key to analyzing the compatibility of the given cations and anions in the question.