미해결 질문
Write a mechanism for the peroxide-catalyzed radical polymerization of vinyl acetate.
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Back-biting results in short branches because it is faster than intermolecular chain transfer.
Intramolecular chain transfer is a controlled reaction and results in a uniform distribution of branches.
Back-biting only takes place in short chains, and therefore produce shorter branches.
Intramolecular H abstraction at the 5th carbon produces a stable transition state.
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