Are the following molecules constitutional isomers?
A
Yes, because they have the same molecular formula, but differ in their connectivity.
B
No, because one is saturated, and the other is unsaturated.
C
No, because they have different numbers of hydrogen atoms.
D
Yes, because they have the same boiling point.
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1
Identify the molecular formula of each molecule. Count the number of carbon (C) and hydrogen (H) atoms in each structure.
For the first molecule, which is a cycloalkane, count the carbons in the ring and any additional carbons in the side chain. Then count the hydrogens.
For the second molecule, which is an alkene, count the number of carbons in the chain and the number of hydrogens, taking into account the double bond.
Compare the molecular formulas of the two molecules. Constitutional isomers have the same molecular formula but different connectivity.
Check the saturation level of each molecule. A saturated molecule has only single bonds, while an unsaturated molecule contains double or triple bonds. This will help determine if they are constitutional isomers.