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Organic Chemistry 2 Final - 6! 1부
샘플
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16. Conjugated Systems / Basics of Molecular Orbital Theory / 문제 9
문제 9

a. Draw the end lobes of molecular orbitals of conjugated π-bonds in the following to show whether the HOMO is symmetric or antisymmetric.
i. A polyene with even numbers of π-bonds.ii. A polyene with odd numbers of π-bonds.
b. Do these MOs follow the Woodward–Hoffmann rules given below?
Woodward–Hoffmann rules:
  • For an even number of π-bonds, an electrocyclic reaction occurs thermally with a conrotatory ring closure and photochemically with disrotatory ring closure.
  • For an odd number of π-bonds electrocyclic reaction thermally with a disrotatory ring closure and photochemically with conrotatory ring closure.