Calculate the amount of energy (in calories) required to flip an 1H nucleus in an NMR spectrometer that operates at 300 MHz.

Understand the relationship between the energy required to flip a nucleus and the frequency of the NMR spectrometer. The energy difference (ΔE) between the two spin states of a nucleus in a magnetic field is given by the equation: ΔE=hν, where h is Planck's constant and ν is the frequency of the spectrometer. Substitute the given frequency of the NMR spectrometer, 300 MHz, into the equation. Convert the frequency from MHz to Hz by multiplying by $$10^{6}. $$Use the value of Planck's constant, h=6.626×$$10^{-34}$$ ext{ J·s}, to calculate the energy difference in joules. Multiply h by the frequency in Hz. Convert the energy from joules to calories. Use the conversion factor: 1 ext{ calorie} = 4.184 ext{ joules}. Divide the energy in joules by 4.184 to obtain the energy in calories. Verify the units and ensure the final value is expressed in calories. This will give the amount of energy required to flip the 1H nucleus in the NMR spectrometer operating at 300 MHz.

Ch. 14 - NMR Spectroscopy

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Bruice 8th Edition

Ch. 14 - NMR Spectroscopy

문제 73

14장, 문제 73

Calculate the amount of energy (in calories) required to flip an ¹H nucleus in an NMR spectrometer that operates at 300 MHz.

검증된 단계별 안내

Understand the relationship between the energy required to flip a nucleus and the frequency of the NMR spectrometer. The energy difference (ΔE) between the two spin states of a nucleus in a magnetic field is given by the equation:

Δ E = h ν

, where

h

is Planck's constant and

ν

is the frequency of the spectrometer.

Substitute the given frequency of the NMR spectrometer, 300 MHz, into the equation. Convert the frequency from MHz to Hz by multiplying by

10

⁶.

Use the value of Planck's constant,

h =6.626×10

^-34 $\text{ J·s}$, to calculate the energy difference in joules. Multiply

h

by the frequency in Hz.

Convert the energy from joules to calories. Use the conversion factor:

1 \(\text{ calorie}\) = 4.184 \(\text{ joules}\)

. Divide the energy in joules by 4.184 to obtain the energy in calories.

Verify the units and ensure the final value is expressed in calories. This will give the amount of energy required to flip the 1H nucleus in the NMR spectrometer operating at 300 MHz.

비슷한 문제에 대한 검증된 영상 답변:

이 영상 해법은 위 문제에 도움이 된다고 튜터들이 추천한 것입니다.

영상 길이:

10m

주요 개념

질문에 올바르게 답하기 위해 반드시 이해해야 하는 핵심 개념들은 다음과 같습니다.

Nuclear Magnetic Resonance (NMR)

Nuclear Magnetic Resonance (NMR) is a spectroscopic technique used to observe the magnetic properties of atomic nuclei. In NMR, nuclei in a magnetic field absorb and re-emit electromagnetic radiation, allowing for the determination of molecular structure. The frequency of the NMR spectrometer, measured in megahertz (MHz), indicates the strength of the magnetic field and influences the energy required to flip the nuclear spin states.

Energy of a Spin Transition

The energy required to flip a nucleus from its lower energy state to a higher energy state in NMR is determined by the relationship between the magnetic field strength and the frequency of the radiation. This energy can be calculated using the formula E = hν, where E is energy, h is Planck's constant, and ν is the frequency of the applied electromagnetic radiation. For a 1H nucleus at 300 MHz, this energy corresponds to the energy difference between the two spin states.

Planck's Constant

Planck's constant (h) is a fundamental constant in quantum mechanics that relates the energy of a photon to its frequency. It has a value of approximately 6.626 x 10^-34 J·s. In the context of NMR, it is essential for calculating the energy required for nuclear spin transitions, as it provides the proportionality factor between energy and frequency, allowing for the conversion of energy units from joules to calories when necessary.