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Cell Potential: ∆G and K
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Cell Potential: ∆G and K
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20. Electrochemistry / Cell Potential: G and K / Problem 3
Problem 3
What are the balanced equation, standard emf, ΔG°, and K value at 298 K for the oxidation of
MnO
2
(s)
to
MnO
4
−
(aq)
by ClO
−
(aq) in basic solution?
A
balanced equation: 2 MnO
2
(s) + 2 OH
−
(aq) + 3 ClO
−
(aq) → 2 MnO
4
−
(aq) + H
2
O(l) + 3 Cl
−
(aq)
E° = 0.30 V
ΔG° =−1.7×10
2
kJ
K = 3×10
30
B
balanced equation: MnO
2
(s) + 2 OH
−
(aq) + ClO
−
(aq) → MnO
4
−
(aq) + H
2
O(l) + Cl
−
(aq)
E° = −0.30 V
ΔG° =1.7×10
2
kJ
K = 4×10
−31
C
balanced equation: 2 MnO
2
(s) + 2 OH
−
(aq) + 3 ClO
−
(aq) → 2 MnO
4
−
(aq) + H
2
O(l) + 3 Cl
−
(aq)
E° = −0.30 V
ΔG° =1.7×10
2
kJ
K = 4×10
−31
D
balanced equation: MnO
2
(s) + 2 OH
−
(aq) + ClO
−
(aq) → MnO
4
−
(aq) + H
2
O(l) + Cl
−
(aq)
E° = 0.30 V
ΔG° =−1.7×10
2
kJ
K = 3×10
30
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