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General Chemistry I – Chapter 4 Practice Problems Study Guide

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Q26. Using the activity series, write balanced chemical equations for the following reactions. If no reaction occurs, write NR.

Background

Topic: Activity Series and Single Displacement Reactions

This question tests your understanding of how to use the activity series of metals to predict whether a single displacement (redox) reaction will occur when a metal is placed in a solution containing another metal's ions.

Activity series of metals in aqueous solution

Key Terms and Concepts:

  • Activity Series: A list of metals ranked by their ability to be oxidized (lose electrons). A metal higher in the series will displace a metal ion lower in the series from solution.

  • Single Displacement Reaction: A reaction where an element reacts with a compound and displaces another element from it.

  • NR: No Reaction occurs if the metal is below the ion in the activity series.

Step-by-Step Guidance

  1. Refer to the activity series table to determine the relative reactivity of the metals involved in each reaction.

  2. Part (a): Iron metal is added to a solution of copper(II) nitrate

    • Find iron (Fe) and copper (Cu) on the activity series.

    • Compare their positions: If Fe is above Cu, Fe can displace Cu2+ from solution.

    • Write the unbalanced equation:

    • Balance the equation for mass and charge.

  3. Part (b): Zinc metal is added to a solution of magnesium sulfate

    • Find zinc (Zn) and magnesium (Mg) on the activity series.

    • Compare their positions: If Zn is below Mg, no reaction will occur.

    • If Zn is above Mg, write the unbalanced equation:

    • Balance the equation if a reaction occurs.

  4. For each part, use the activity series to justify whether a reaction occurs or not, and set up the balanced equation if it does.

Try solving on your own before revealing the answer!

Final Answer:

(a) Iron metal is added to a solution of copper(II) nitrate:

Iron is above copper in the activity series, so a reaction occurs.

Balanced equation:

(b) Zinc metal is added to a solution of magnesium sulfate:

Zinc is below magnesium in the activity series, so no reaction (NR) occurs.

The activity series helps predict whether a metal can displace another from solution based on their relative positions.

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