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Matter, Measurements, and Atomic Structure: General Chemistry Study Guide

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Matter and Its Classification

Definition and States of Matter

Matter is defined as anything that has mass and occupies space. It exists in three primary states, each with distinct physical properties.

  • Solid: Has a definite shape and volume; particles are closely packed and vibrate in place.

  • Liquid: Has a definite volume but takes the shape of its container; particles are less tightly packed and can move past one another.

  • Gas: Has neither definite shape nor volume; particles are far apart and move freely.

Classification of Matter

Matter can be classified as pure substances or mixtures. Pure substances have a fixed composition and can be further divided into elements and compounds.

  • Element: A substance that cannot be broken down by chemical means. Examples include hydrogen (H), oxygen (O).

  • Compound: A substance composed of two or more elements chemically combined in fixed proportions. Examples: water (H2O), carbon dioxide (CO2).

Example: Water (H2O) is a compound formed from hydrogen and oxygen.

Atomic Structure and the Periodic Table

Atoms and Subatomic Particles

Atoms are the basic units of matter, composed of three main subatomic particles:

  • Proton: Positively charged particle located in the nucleus.

  • Neutron: Neutral particle also found in the nucleus.

  • Electron: Negatively charged particle that orbits the nucleus.

The nucleus contains protons and neutrons, while electrons move in regions around the nucleus.

The Periodic Table

The periodic table organizes elements by their atomic number, which is the number of protons in the nucleus. Elements are arranged in rows (periods) and columns (groups) based on similar properties.

  • Atomic Number: Number of protons in an atom; determines the element's identity.

Chemical Bonds

Ionic and Covalent Bonds

Chemical bonds are forces that hold atoms together in compounds. The two main types are:

  • Ionic Bond: Formed when electrons are transferred from a metal to a nonmetal, resulting in oppositely charged ions that attract each other.

  • Covalent Bond: Formed when atoms share pairs of electrons, typically between nonmetals.

Example: Sodium chloride (NaCl) is formed by an ionic bond between sodium (Na) and chlorine (Cl).

Measurements and Units

SI Units

The International System of Units (SI) is used for scientific measurements. The fundamental SI units include:

  • Meter (m): Unit of length

  • Kilogram (kg): Unit of mass

  • Second (s): Unit of time

  • Kelvin (K): Unit of temperature

  • Mole (mol): Unit for amount of substance

Significant Figures

Significant figures indicate the precision of a measurement. The number of significant digits reflects the certainty in the measured value.

  • Rule: All nonzero digits are significant; zeros between nonzero digits are significant; leading zeros are not significant; trailing zeros in a decimal number are significant.

Example: 0.00450 has three significant figures.

Density

Density is a physical property defined as mass per unit volume. It is used to characterize substances and can be calculated using the following formula:

  • Formula:

  • Where: d is density, m is mass, and V is volume.

Example: If a sample has a mass of 10 g and a volume of 2 cm3, its density is .

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