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Alkene, Alkyne, and Conjugated Pi System Chemistry: Addition Reactions, Mechanisms, and Properties

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Electrophilic Aromatic Substitution – General Mechanism

  • EAS General Mechanism
    06:52
  • EAS Review
    03:07

Markovnikov's Rule

  • Provide the mechanism
    01:26
  • How to add to asymmetrical double bonds.
    03:38

Hydrohalogenation

  • General properties of hydrohalogenation.
    04:07
  • Provide the mechanism
    02:24

Radical Hydrohalogenation

  • Provide the complete mechanism for the following radical hydrohalogenation.
    02:53
  • How Radical Hydrohalogenation is different from typical Hydrohalogenation.
    07:13
  • Overview of Hydrohalogention.
    01:18

Radical Initiators

  • What are Radical Initiators?
    03:49
  • Heterolytic vs. Homolytic Bond Cleavage .
    04:39

Radical Stability

  • The radical stability trend.
    03:43
  • Determine which of the following radicals is the most stable.
    03:25

Radical Chain Reaction

  • The one reaction that alkanes will actually undergo.
    02:05
  • Explaining the following problem.
    00:34
  • Show the entire chain reaction mechanism.
    04:08

Hydroboration-Oxidation

  • General properties of hydroboration-oxidation.
    06:38
  • Acid-catalyzed hydroboration-oxidation mechanism
    06:14

Catalytic Hydrogenation and Wilkinson's Catalyst

  • General properties of catalytic hydrogenation.
    05:21

Weak Oxidative Cleavage

  • General properties of ozonolysis.
    06:30

Cycloalkanes

  • Name the following alkane
    00:53
  • Determining Root Name
    00:18
  • Determining Root Name
    00:34

Resonance Structures

  • How to draw a resonance hybrid.
    03:24
  • The rules you need for resonance:
    03:34
  • How to determine which structure is most stable.
    01:32

Resonance Structures

  • How to draw a resonance hybrid.
    03:24
  • The rules you need for resonance:
    03:34
  • How to determine which structure is most stable.
    01:32

Alkyne Hydration

  • Vinyl alcohols yield tautomers.
    03:51
  • Markovnikov addition of alcohols yields ketones.
    03:29

Alkynide Alkylation

  • Sodium Alkynide Alkylation
    03:19

Alkyne Hydrohalogenation

  • Double hydrohalogenation of alkynes.
    02:20
  • General properties of double addition reactions to alkynes.
    01:01

Alkynide Synthesis and Retrosynthesis

  • Predict the major product.
    03:25
  • Provide the reagents needed
    04:17
  • Predict the major product.
    05:09

Alkyne Halogenation

  • Double halogenation of alkynes.
    02:15

Alkyne Oxidative Cleavage

  • General features of alkyne cleavage.
    02:13
  • Predict the product of the following reaction.
    03:50