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Reactions of Aromatic Compounds: Electrophilic and Nucleophilic Substitution, Coupling, and Addition Mechanisms

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Electrophilic Aromatic Substitution – General Mechanism

  • EAS General Mechanism
    06:52
  • EAS Review
    03:07

EAS – Monosubstituted Benzene

  • Badass Activity Chart
    11:55
  • Activity and Directing Effects
    04:29

EAS-o, p-Major Products

  • Ortho, Para major products
    04:42

Generating Electrophiles – EAS Nitration

  • Reduction of Nitro Groups
    03:23
  • EAS Nitration
    06:09

Side-Chain Oxidation

  • Benzylic Oxidation
    03:20
  • Which alkylbenzene would NOT yield benzoic acid, treated with KMnO4
    00:49

Birch Reduction

  • Regiospecific products
    02:51
  • Birch Reduction Mechanism
    04:40

Reactions at Benzylic Positions

  • Percorso guidato
    Reactions at Benzylic Positions Example 3
    1:12
  • Percorso guidato
    Reactions at Benzylic Positions Example 2
    2:03
  • Percorso guidato
    Reactions at Benzylic Positions Concept 1
    1:01

Cross-Coupling General Reactions

  • Overview of Cross-Coupling General Reactions
    04:10
  • Cross-Coupling Reaction Mechanisms
    03:28
  • Cross-Coupling Reaction Mechanisms Example 3
    02:46

Heck Reaction

  • Heck Reaction Example 1
    03:50
  • Heck Reaction
    02:30
  • Heck Reaction Mechanism Example 1
    07:35

Suzuki Reaction

  • Suzuki Reaction Example 1
    03:58
  • Suzuki Reaction
    04:02
  • Suzuki Reaction
    03:22

SNAr Addition-Elimination Mechanism

  • The Meisenheimer Complex
    06:23
  • Which ipso-substitution is more favored
    03:30
  • General Mechanism
    06:45

Benzyne Pathway – General Mechanism

  • Regiospecificity
    03:20
  • General Mechanism
    06:06
  • Activating and deactivating groups
    03:27