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Structure and Stereochemistry of Alkanes: Study Notes

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Functional Groups

  • Assigning Degrees to Alkyl Halides
    01:30
  • Why we need functional groups.
    01:49
  • The difference between aldehydes and ketones.
    03:08

Common Substituents

  • Name the following alkane
    02:33
  • Understanding Non-IUPAC Substituents
    06:42
  • Name the following alkane
    03:56

Constitutional Isomers

  • Isomeric Relationships
    03:28
  • Using the flowchart to determine isometric relationships.
    05:02
  • Isomeric Relationships
    02:56

Alkane Nomenclature

  • Naming the root chain
    01:02
  • Provide the IUPAC name for the following alkane
    07:08
  • The different parts of an IUPAC name
    03:43

Common Substituents

  • Name the following alkane
    02:33
  • Understanding Non-IUPAC Substituents
    06:42
  • Name the following alkane
    03:56

Common Substituents

  • Name the following alkane
    02:33
  • Understanding Non-IUPAC Substituents
    06:42
  • Name the following alkane
    03:56

Newman Projections – Conformational Energy

  • How to draw a Newman Projection Energy Diagram.
    07:27
  • How sigma bond rotation is visualized
    03:11
  • The energy states of 3 different Newman Projections.
    03:51

Conformations

  • Understanding what a conformer is.
    03:29

Cycloalkanes

  • Name the following alkane
    00:53
  • Determining Root Name
    00:18
  • Determining Root Name
    00:34

Cyclohexane – Determination of Cis and Trans

  • Is the following cyclohexane cis or trans?
    00:44
  • How to draw chairs.
    01:18
  • Is the following cyclohexane cis or trans?
    00:27

Cyclohexane – Chairs and Positions

  • What is a chair conformation?
    01:05
  • How chairs flip from one conformation to another
    02:22
  • How chairs flip from one conformation to another
    04:26

Chair Flip

  • The 3 important factors when drawing chairs
    05:12

1H NMR - Total Number of Signals

  • General Assumption for 1H NMR Signals
    04:35
  • Identifying Proton Signals
    02:02
  • Identifying Proton Signals
    01:55