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Ch. 11 - Properties and Synthesis of Alkyl Halides: Radical Reactions
Mullins - Organic Chemistry: A Learner Centered Approach 1st Edition
Mullins1st EditionOrganic Chemistry: A Learner Centered ApproachISBN: 9780137566471Non è quello che usi tu?Cambia libro di testo
Capitolo 10, Problema 41b

Which of the reactions studied in this chapter result in oxidation of the organic molecule? Justify your answer.
(b)

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1
Identify the type of reaction: The reaction shown is an addition reaction where HBr is added across the double bond of an alkene.
Determine the change in oxidation state: In organic chemistry, oxidation is typically associated with an increase in the number of bonds to oxygen or a decrease in the number of bonds to hydrogen. Here, the alkene is converted to an alkyl bromide.
Analyze the oxidation state of carbon: In the alkene, each carbon of the double bond is bonded to two hydrogens and one carbon. In the product, one of these carbons is now bonded to a bromine atom instead of a hydrogen.
Evaluate the effect of bromine: Bromine is more electronegative than hydrogen, but the addition of bromine does not increase the oxidation state of carbon in the same way that adding oxygen would. Therefore, this reaction does not result in oxidation.
Conclude the analysis: Since the reaction involves the addition of HBr without an increase in the oxidation state of carbon, it is not considered an oxidation reaction.

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