(a) To identify a liquid substance, a student determined its density. Using a graduated cylinder, she measured out a 45-mL sample of the substance. She then measured the mass of the sample, finding that it weighed 38.5 g. She knew that the substance had to be either isopropyl alcohol 1density 0.785 g/mL² or toluene (density 0.866 g/mL). What are the calculated density and the probable identity of the substance?

(b) Carbon dioxide (CO₂) is a gas at room temperature and pressure. However, carbon dioxide can be put under pressure to become a 'supercritical fluid' that is a much safer dry-cleaning agent than tetrachloroethylene. At a certain pressure, the density of supercritical CO₂ is 0.469 g/cm³. What is the mass of a 25.0-mL sample of supercritical CO₂ at this pressure?

(c) Is a graduated cylinder such as that shown in Figure 1.21 likely to afford the accuracy of measurement needed?

(d) A cubic piece of metal measures 5.00 cm on each edge. If the metal is nickel, whose density is 8.90 g/cm³, what is the mass of the cube?

(a) A sample of tetrachloroethylene, a liquid used in dry cleaning that is being phased out because of its potential to cause cancer, has a mass of 40.55 g and a volume of 25.0 mL at 25 °C. What is its density at this temperature? Will tetrachloroethylene float on water? (Materials that are less dense than water will float.)

(b) An experiment requires 45.0 g of ethylene glycol, a liquid whose density is 1.114 g/mL. Rather than weigh the sample on a balance, a chemist chooses to dispense the liquid using a graduated cylinder. What volume of the liquid should he use?