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Ch.14 - Chemical Kinetics
Brown - Chemistry: The Central Science 14th Edition
Brown14th EditionChemistry: The Central ScienceISBN: 9780134414232Non è quello che usi tu?Cambia libro di testo
Tutti i libri di testoBrown 14th EditionCh.14 - Chemical KineticsProblema 19a
Capitolo 14, Problema 19a

Consider the following hypothetical aqueous reaction: A(aq) → B(aq). A flask is charged with 0.065 mol of A in a total volume of 100.0 mL. The following data are collected: Time (min) 0 10 20 30 40 Moles of A 0.065 0.051 0.042 0.036 0.031 (a) Calculate the number of moles of B at each time in the table, assuming that there are no molecules of B at time zero and that A cleanly converts to B with no intermediates.
Table showing time in seconds and corresponding moles of C for a chemical reaction.

Guida verificata passo dopo passo
1
Step 1: Understand the reaction A(aq) -> B(aq) and note that initially, there are 0.065 moles of A and 0 moles of B.
Step 2: Recognize that as the reaction proceeds, the moles of A decrease and the moles of B increase by the same amount since A converts to B with no intermediates.
Step 3: For each time point, calculate the change in moles of A by subtracting the moles of A at that time from the initial moles of A (0.065 moles).
Step 4: The change in moles of A is equal to the moles of B formed at each time point. Use this to determine the moles of B at each time point.
Step 5: Record the moles of B at each time point: 0, 10, 20, 30, and 40 minutes.

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Stoichiometry

Stoichiometry is the calculation of reactants and products in chemical reactions. It is based on the balanced chemical equation, which shows the ratio of moles of each substance involved. In this case, knowing the initial moles of A and the moles of B produced allows for the determination of the moles of B at various times as A is consumed.
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Stoichiometry Concept

Concentration and Molarity

Concentration refers to the amount of a substance in a given volume of solution, typically expressed in molarity (M), which is moles of solute per liter of solution. In this problem, the initial concentration of A is crucial for calculating how much of A has reacted over time and how much B has formed, as the reaction proceeds in a closed system.
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Molarity Concept

Reaction Kinetics

Reaction kinetics studies the rates of chemical reactions and the factors affecting them. In this scenario, the time intervals provided allow for the observation of how the concentration of A decreases and how the concentration of B increases, illustrating the relationship between the rate of reaction and the change in concentration of reactants and products over time.
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Chemical Kinetics
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Domanda del libro di testo

Consider the following hypothetical aqueous reaction: A(aq) → B(aq). A flask is charged with 0.065 mol of A in a total volume of 100.0 mL. The following data are collected: Time (min) 0 10 20 30 40 Moles of A 0.065 0.051 0.042 0.036 0.031 (b) Calculate the average rate of disappearance of A for each 10-min interval in units of M>s.

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(c) As a reaction proceeds, does the instantaneous reaction rate increase or decrease?

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(b) As the temperature increases, does the reaction rate increase or decrease?

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(a) What are the units usually used to express the rates of reactions occurring in solution?

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Consider the following hypothetical aqueous reaction: A(aq) → B(aq). A flask is charged with 0.065 mol of A in a total volume of 100.0 mL. The following data are collected: Time (min) 0 10 20 30 40 Moles of A 0.065 0.051 0.042 0.036 0.031 (c) Between t = 10 min and t = 30 min, what is the average rate of appearance of B in units of M/s? Assume that the volume of the solution is constant.

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A flask is charged with 0.100 mol of A and allowed to react to form B according to the hypothetical gas-phase reaction A1g2¡B1g2. The following data are collected: Time (s) 0 40 80 120 160 Moles of A 0.100 0.067 0.045 0.030 0.020 (c) Which of the following would be needed to calculate the rate in units of concentration per time: (i) the pressure of the gas at each time, (ii) the volume of the reaction flask, (iii) the temperature, or (iv) the molecular weight of A?

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