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Ch.16 - Acid-Base Equilibria
Brown - Chemistry: The Central Science 14th Edition
Brown14th EditionChemistry: The Central ScienceISBN: 9780134414232Non è quello che usi tu?Cambia libro di testo
Capitolo 16, Problema 94

The fluoride ion reacts with water to produce HF. (c) Is fluoride acting as a Lewis acid or as a Lewis base when reacting with water?

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1
Understand the concept of Lewis acids and bases: A Lewis acid is a substance that can accept a pair of electrons, while a Lewis base is a substance that can donate a pair of electrons.
Identify the role of fluoride ion (F⁻) in the reaction: The fluoride ion has a lone pair of electrons that it can donate.
Consider the reaction between fluoride ion and water: F⁻ + H₂O ⇌ HF + OH⁻.
Analyze the interaction: The fluoride ion donates its lone pair of electrons to a hydrogen atom from water, forming HF.
Conclude the role of fluoride: Since the fluoride ion donates a pair of electrons, it is acting as a Lewis base in this reaction.

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Lewis Acids and Bases

Lewis acids are substances that can accept an electron pair, while Lewis bases are those that can donate an electron pair. This theory expands the definition of acids and bases beyond the traditional Brønsted-Lowry definitions, allowing for a broader understanding of chemical reactivity. In this context, identifying whether a species acts as a Lewis acid or base is crucial for predicting the outcome of chemical reactions.
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Lewis Acids and Bases

Fluoride Ion (F-)

The fluoride ion (F-) is a negatively charged ion formed when fluorine gains an electron. It is a strong Lewis base due to its high electron density, which allows it to readily donate an electron pair to electron-deficient species. Understanding the properties of fluoride is essential for analyzing its behavior in reactions, particularly its interaction with water.
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Hydrolysis of Fluoride Ion

When fluoride ions react with water, they undergo hydrolysis, leading to the formation of hydrofluoric acid (HF). This reaction involves the fluoride ion donating an electron pair to a hydrogen ion from water, illustrating its role as a Lewis base. Recognizing this process is key to determining the acid-base behavior of fluoride in aqueous solutions.
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Indicate whether each of the following statements is true or false. For each statement that is false, correct the statement to make it true. (a) In general, the acidity of binary acids increases from left to right in a given row of the periodic table. (b) In a series of acids that have the same central atom, acid strength increases with the number of hydrogen atoms bonded to the central atom. (c) Hydrotelluric acid 1H2Te2 is a stronger acid than H2S because Te is more electronegative than S.

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Indicate whether each of the following statements is true or false. For each statement that is false, correct the statement to make it true. (a) Acid strength in a series of H¬A molecules increases with increasing size of A. (b) For acids of the same general structure but differing electronegativities of the central atoms, acid strength decreases with increasing electronegativity of the central atom. (c) The strongest acid known is HF because fluorine is the most electronegative element.

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Identify the Lewis acid and Lewis base among the reactants in each of the following reactions:

(a) Fe(ClO4)3(s) + 6 H2O(l) ⇌ [Fe(H2O)6]3+(aq) + 3 ClO4-(aq)

(b) CN-(aq) + H2O(l) ⇌ HCN(aq) + OH-(aq)

(c) (CH3)3N(g) + BF3(g) ⇌ (CH3)NBF3(s)

(d) HIO(lq) + NH2-(lq) ⇌ NH3(lq) + IO-(lq) (lq denotes liquid ammonia as solvent)

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Identify the Lewis acid and Lewis base in each of the following reactions:

(a) HNO2(aq) + OH-(aq) ⇌ NO2-(aq) + H2O(l)

(b) FeBr3(s) + Br-(aq) ⇌ FeBr4-(aq)

(c) Zn2+(aq) + 4 NH3(aq) ⇌ Zn(NH3)42+(aq)

(d) SO2(g) + H2O(l) ⇌ H2SO3(aq)

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