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Ch.17 - Additional Aspects of Aqueous Equilibria
Brown - Chemistry: The Central Science 14th Edition
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Tutti i libri di testoBrown 14th EditionCh.17 - Additional Aspects of Aqueous EquilibriaProblema 81b
Capitolo 17, Problema 81b

(b) What is the most significant difference between the sulfides precipitated in group 2 and those precipitated in group 3?
Flowchart illustrating selective precipitation of metal cations in groups 1 to 5.

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Identify the sulfides precipitated in Group 2: CuS, CdS, Bi2S3, PbS, HgS, As2S3, Sb2S3, SnS2.
Identify the sulfides precipitated in Group 3: ZnS, NiS, MnS, CoS.
Note that Group 2 sulfides are precipitated in acidic conditions (H2S and 0.2 M HCl).
Note that Group 3 sulfides are precipitated in basic conditions (NH4)2S at pH = 8.0.
The most significant difference is the pH condition under which the sulfides precipitate: Group 2 sulfides precipitate in acidic conditions, while Group 3 sulfides precipitate in basic conditions.

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Selective Precipitation

Selective precipitation is a technique used in analytical chemistry to separate ions in a solution based on their solubility. By adding specific reagents, certain ions will form insoluble compounds (precipitates) while others remain dissolved. This method is crucial for distinguishing between different groups of metal cations, as seen in the flowchart, which outlines the sequential addition of reagents to precipitate specific groups.
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Group 2 vs. Group 3 Sulfides

The sulfides precipitated in Group 2 are primarily acid-insoluble, meaning they do not dissolve in acidic conditions, while those in Group 3 are base-insoluble, indicating they remain undissolved in basic conditions. This distinction is significant because it affects the conditions under which these sulfides can be separated and identified during qualitative analysis, as shown in the flowchart.
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Alkyl Groups

Precipitation Reagents

Precipitation reagents are chemicals added to a solution to induce the formation of a solid precipitate from dissolved ions. In the context of the flowchart, reagents like H2S and (NH4)2S are used to selectively precipitate sulfides from different groups of metal cations. Understanding the role of these reagents is essential for effectively separating and identifying metal ions in a mixture.
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