Suggest how the cations in each of the following solution mixtures can be separated: (c) Pb2 + and Al3 +.
Brown 14th Edition
Ch.17 - Additional Aspects of Aqueous Equilibria
Problema 79c,dIn the course of various qualitative analysis procedures, the following mixtures are encountered: (c) Mg2+ and K+ (d) Ag+ and Mn2+. Suggest how each mixture might be separated.
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Concetti chiave
Qualitative Analysis
Precipitation Reactions
Solubility Rules
(b) What is the most significant difference between the sulfides precipitated in group 2 and those precipitated in group 3?
Derive an equation similar to the Henderson–Hasselbalch equation relating the pOH of a buffer to the pKb of its base component.
A solution containing several metal ions is treated with dilute HCl; no precipitate forms. The pH is adjusted to about 1, and H2S is bubbled through. Again, no precipitate forms. The pH of the solution is then adjusted to about 8. Again, H2S is bubbled through. This time a precipitate forms. The filtrate from this solution is treated with (NH4)2HPO4. No precipitate forms. Which of these metal cations are either possibly present or definitely absent: Al3+, Na+, Ag+, Mg2+?
In the course of various qualitative analysis procedures, the following mixtures are encountered: (a) Zn2+ and Cd2+. (b) Cr(OH)3 and Fe(OH)3 Suggest how each mixture might be separated.