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Ch.8 - Basic Concepts of Chemical Bonding
Brown - Chemistry: The Central Science 14th Edition
Brown14th EditionChemistry: The Central ScienceISBN: 9780134414232Non è quello che usi tu?Cambia libro di testo
Capitolo 8, Problema 44

The iodine monobromide molecule, IBr, has a bond length of 249 pm and a dipole moment of 1.21 D. (a) Which atom of the molecule is expected to have a negative charge?

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Identify the atoms in the IBr molecule: iodine (I) and bromine (Br).
Recall that the dipole moment is a measure of the separation of positive and negative charges in a molecule.
Understand that the dipole moment points from the positive to the negative charge.
Consider the electronegativity of the atoms: Bromine (Br) is more electronegative than iodine (I).
Conclude that the more electronegative atom, bromine (Br), will have a partial negative charge, while iodine (I) will have a partial positive charge.

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Electronegativity

Electronegativity is a measure of an atom's ability to attract and hold onto electrons in a chemical bond. In the case of IBr, iodine (I) is less electronegative than bromine (Br), meaning that Br will attract the shared electrons more strongly, leading to a partial negative charge on the bromine atom.
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Electronegativity Trends

Dipole Moment

The dipole moment is a vector quantity that represents the separation of positive and negative charges in a molecule. It is calculated as the product of the charge and the distance between the charges. In IBr, the dipole moment of 1.21 D indicates that there is an uneven distribution of electron density, confirming that one atom carries a partial negative charge.
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Bond Polarity

Bond polarity refers to the distribution of electrical charge over the atoms joined by the bond. In IBr, the difference in electronegativity between bromine and iodine results in a polar covalent bond, where bromine becomes partially negative and iodine partially positive, leading to the overall dipole moment observed in the molecule.
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Molecular Polarity
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