Ch.23 - Organic and Biological Chemistry
McMurry8th EditionChemistryISBN: 9781292336145
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TOC.tableOfContents
- Ch.1 - Chemical Tools: Experimentation & Measurement170
- Ch.2 - Atoms, Molecules & Ions160
- Ch.3 - Mass Relationships in Chemical Reactions169
- Ch.4 - Reactions in Aqueous Solution199
- Ch.5 - Periodicity & Electronic Structure of Atoms102
- Ch.6 - Ionic Compounds: Periodic Trends and Bonding Theory92
- Ch.7 - Covalent Bonding and Electron-Dot Structures61
- Ch.8 - Covalent Compounds: Bonding Theories and Molecular Structure59
- Ch.9 - Thermochemistry: Chemical Energy122
- Ch.10 - Gases: Their Properties & Behavior155
- Ch.11 - Liquids & Phase Changes54
- Ch.12 - Solids and Solid-State Materials73
- Ch.13 - Solutions & Their Properties120
- Ch.14 - Chemical Kinetics98
- Ch.15 - Chemical Equilibrium125
- Ch.16 - Aqueous Equilibria: Acids & Bases110
- Ch.17 - Applications of Aqueous Equilibria147
- Ch.18 - Thermodynamics: Entropy, Free Energy & Equilibrium86
- Ch.19 - Electrochemistry154
- Ch.20 - Nuclear Chemistry96
- Ch.21 - Transition Elements and Coordination Chemistry156
- Ch.22 - The Main Group Elements187
- Ch.23 - Organic and Biological Chemistry51
Capitolo 23, Problema 84
Which of the following compounds are capable of cis–trans isomerism? (a) 1-Hexene (b) 2-Hexene (c) 3-Hexene
Guida verificata passo dopo passo1
Identify the structural requirement for cis-trans isomerism: a compound must have a double bond with each carbon of the double bond attached to two different groups.
Examine 1-Hexene: The double bond is between the first and second carbon atoms. Since the first carbon is attached to two hydrogen atoms, it cannot have cis-trans isomers.
Examine 2-Hexene: The double bond is between the second and third carbon atoms. Each of these carbons is attached to different groups, allowing for cis-trans isomerism.
Examine 3-Hexene: The double bond is between the third and fourth carbon atoms. Each of these carbons is attached to different groups, allowing for cis-trans isomerism.
Conclude which compounds can exhibit cis-trans isomerism based on the analysis of their structures.
Concetti chiave
Ecco i concetti essenziali che devi comprendere per rispondere correttamente alla domanda.
Cis-Trans Isomerism
Cis-trans isomerism, also known as geometric isomerism, occurs in compounds with restricted rotation around a double bond or a ring structure. In this type of isomerism, the spatial arrangement of substituents differs, leading to distinct physical and chemical properties. The 'cis' configuration has similar groups on the same side, while the 'trans' configuration has them on opposite sides.
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Percorso guidato
3:33
Isomerism in Coordination Complexes Example
Alkenes and Double Bonds
Alkenes are hydrocarbons that contain at least one carbon-carbon double bond (C=C). The presence of this double bond is crucial for cis-trans isomerism, as it restricts the rotation of the carbon atoms involved. The position of substituents around the double bond determines whether the compound can exhibit geometric isomerism.
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Percorso guidato
02:47Rules for Naming Alkenes
Substituent Positioning
For a compound to exhibit cis-trans isomerism, it must have two different substituents attached to each carbon of the double bond. If both carbons in the double bond have identical substituents, cis-trans isomerism cannot occur. Therefore, analyzing the structure of the given compounds is essential to determine their capability for geometric isomerism.
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Percorso guidato
01:33Lone Pair Positions
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