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All of the following solutions form a buffer except:I. 1.0 M H2CO3 and 1.0 M NaHCO3II. 1.0 M CH3NH2 and 1.0 M CH3NH3ClIII. 1.0 M NaOH and 1.0 M HBrIV. 1.0 M CH3NH2 and 1.0 M HBrV. 1.0 M H3PO4 and 1.0 M NaH2PO4

All of the following solutions form a buffer except:
I. 1.0 M H₂CO₃ and 1.0 M NaHCO₃
II. 1.0 M CH₃NH₂ and 1.0 M CH₃NH₃Cl
III. 1.0 M NaOH and 1.0 M HBr
IV. 1.0 M CH₃NH₂ and 1.0 M HBr
V. 1.0 M H₃PO₄ and 1.0 M NaH₂PO₄