IndietroOrganic Chemistry Exam 1 Practice – Step-by-Step Study Guidance
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Q3. Suppose a particular AB3 molecule has the following resonance structure. How many steric groups are there around the A atom?
Background
Topic: Molecular Geometry and Resonance Structures
This question tests your understanding of resonance structures and the concept of steric groups (regions of electron density) around a central atom, which is important for predicting molecular shape and hybridization.

Key Terms and Formulas
Steric group: Any region of electron density around a central atom, including bonds (single, double, triple) and lone pairs.
Resonance structure: A way of representing delocalized electrons within molecules where more than one valid Lewis structure can be drawn.
Lewis structure: A diagram showing the arrangement of atoms and electrons in a molecule.
Step-by-Step Guidance
Examine the resonance structure provided. Identify all bonds and lone pairs around the central atom (A).
Count each bond (single, double, or triple) as one steric group, regardless of bond order.
Include any lone pairs on the central atom as additional steric groups.
Sum the total number of steric groups (bonds + lone pairs) around atom A.
Use this count to predict the geometry (e.g., trigonal planar, tetrahedral, etc.) if needed.
Try solving on your own before revealing the answer!
Final Answer: 3 steric groups
In the given resonance structure, atom A is bonded to three B atoms (one double bond and two single bonds). There are no lone pairs shown on A, so the total number of steric groups is 3.
This means the geometry around A is trigonal planar.