Domanda del libro di testo
Show the products of the following acetylide alkylation reactions. [Make sure your product has the correct number of carbons.]
(c)
919
views
Ch. 10 - Alkynes: Electrophilic Addition and Redox Reactions
Mullins1st EditionOrganic Chemistry: A Learner Centered ApproachISBN: 9780137566471
Non è quello che usi tu?Cambia libro di testoScegli un libro di testo diverso
TOC.tableOfContents
- Ch. 2 - General Chemistry Translated: Finding the Electrons114
- Ch. 3 - Alkanes and Cycloalkanes: Properties and Conformational Analysis109
- Ch. 4 - Acids and Bases/Electron Flow144
- Ch. 5 - Chemical Reaction Analysis: Thermodynamics and Kinetics118
- Ch. 6 - Stereoisomerism: Arrangement of Atoms in Space112
- Ch. 7 - Principles of Green (Organic) Chemistry3
- Ch. 8 - Alkenes 1: Properties and Electrophilic Additions158
- Ch. 9 - Alkenes 2: Oxidation and Reduction150
- Ch. 10 - Alkynes: Electrophilic Addition and Redox Reactions101
- Ch. 11 - Properties and Synthesis of Alkyl Halides: Radical Reactions108
- Ch. 12 - Substitution and Elimination: Reactions of Haloalkanes172
- Ch. 13 - Alcohols, Ethers and Related Compounds: Substitution and Elimination239
- Ch. 14 - Structural Identification 1: Infrared Spectroscopy and Mass Spectrometry54
- Ch. 15 - Structural Identification 2: Nuclear Magnetic Resonance Spectroscopy93
- Ch. 16 - Metals in Organic Chemistry48
- Ch. 17 - Carbonyl Addition Reactions: Aldehydes and Ketones45
- Ch. 18 - Nucleophilic Acyl Substitution 1: Carboxylic Acids18
- Ch. 19 - Nucleophilic Acyl Substitution 2: Carboxylic Acid Derivatives39
- Ch. 20 - Enolates: Carbonyl Addition and Substitution13
- Ch. 21 - Conjugated Systems 1: Stability and Addition Reactions56
- Ch. 22 - Conjugated Systems 2: Pericyclic Reactions54
- Ch. 23 - Benzene 1: Aromatic Stability and Substitution Reactions64
- Ch. 24 - Benzene 2: Reactions Influenced by the Aromatic Ring62
- Ch. 25 - Amines: Structure, Reactions, and Synthesis27
- Ch. 26 - Amino Acids, Proteins, and Peptide Synthesis9
- Ch. 27 - Carbohydrates, Nucleic Acids, and Lipids54
Mullins1st EditionOrganic Chemistry: A Learner Centered ApproachISBN: 9780137566471Non è quello che usi tu?Cambia libro di testo
Tutti i libri di testo
Mullins 1st EditionCh. 10 - Alkynes: Electrophilic Addition and Redox ReactionsProblema 45a
Mullins 1st EditionCh. 10 - Alkynes: Electrophilic Addition and Redox ReactionsProblema 45aCapitolo 9, Problema 45a
Show the products of the following acetylide alkylation reactions. [Make sure your product has the correct number of carbons.]
(a) 
Guida verificata passo dopo passo1
Step 1: Understand the concept of acetylide alkylation. Acetylide ions (R-C≡C⁻) are strong nucleophiles that can attack alkyl halides (R-X) in an SN2 reaction, leading to the formation of a new carbon-carbon bond.
Step 2: Identify the acetylide ion and the alkyl halide in the reaction. The acetylide ion is typically generated from a terminal alkyne (R-C≡CH) by deprotonation using a strong base like NaNH₂ or NaH.
Step 3: Write the mechanism of the SN2 reaction. The acetylide ion attacks the carbon atom bonded to the halogen in the alkyl halide, displacing the halide ion (X⁻) and forming a new bond between the acetylide carbon and the alkyl group.
Step 4: Count the number of carbons in the product. Add the number of carbons in the acetylide ion to the number of carbons in the alkyl halide to ensure the product has the correct number of carbons.
Step 5: Draw the structure of the product. Combine the acetylide group (R-C≡C⁻) with the alkyl group from the alkyl halide, ensuring the triple bond remains intact and the connectivity is correct.
Risposta video verificata per un problema simile:
Questa soluzione video è stata consigliata dai nostri tutor come utile per risolvere questo problema.
Durata del video:
2mConcetti chiave
Ecco i concetti essenziali che devi comprendere per rispondere correttamente alla domanda.
Acetylide Ion
An acetylide ion is a negatively charged species formed by deprotonating a terminal alkyne. It is a strong nucleophile, capable of attacking electrophiles in nucleophilic substitution reactions. Understanding how to generate and utilize acetylide ions is crucial for performing alkylation reactions effectively.
Video consigliato:
Percorso guidato
3:39
Metal Ion Catalysis Concept 1
Nucleophilic Substitution
Nucleophilic substitution is a fundamental reaction mechanism in organic chemistry where a nucleophile replaces a leaving group in a molecule. In the context of acetylide alkylation, the acetylide ion acts as the nucleophile, attacking an alkyl halide to form a new carbon-carbon bond. This process is essential for extending carbon chains in organic synthesis.
Video consigliato:
01:47Nucleophiles and Electrophiles can react in Substitution Reactions.
Carbon Count in Products
Maintaining the correct number of carbons in the product is vital in organic synthesis, as it ensures the integrity of the molecular structure. In acetylide alkylation, the number of carbons in the starting materials and the alkyl halide must be accounted for to predict the final product accurately. This concept is crucial for verifying the success of the reaction and understanding the resulting compound's properties.
Video consigliato:
07:07Electron Counting
Pratica correlata
Domanda del libro di testo
For the alkynes shows here, show the product(s) expected to form when treated under the following conditions: (v) HCl (2 equiv.). If you expect two products, show both.
(c)
1078
views
Domanda del libro di testo
For the alkynes shows here, show the product(s) expected to form when treated under the following conditions: (ix) Br2 (2 equiv.). If you expect two products, show both.
(f)
988
views
Domanda del libro di testo
Show the products of the following acetylide alkylation reactions. [Make sure your product has the correct number of carbons.]
(d)
665
views
Domanda del libro di testo
Show the products of the following acetylide alkylation reactions. [Make sure your product has the correct number of carbons.]
(b)
788
views
Domanda del libro di testo
For the alkynes shows here, show the product(s) expected to form when treated under the following conditions: (vi) H2SO4, HgSO4, H2O. If you expect two products, show both.
(c)
1121
views