The graph in FIGURE EX40.15 shows the potential-energy function U(x) of a particle. Solution of the Schrödinger equation finds that the n = 3 level has E3 = 0.5 eV and that the n = 6 level has E6 = 2.0 eV. Redraw this figure and add to it the energy lines for the n = 3 and n = 6 states.
Ch 40: One-Dimensional Quantum Mechanics
Knight Calc5th EditionPhysics for Scientists and EngineersISBN: 9780137344796Non è quello che usi tu?Cambia libro di testo
Capitolo 40, Problema 17a
INT An electron is confined in a harmonic potential well that has a spring constant of 2.0 N/m. What are the first three energy levels of the electron?
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Step 1: Recognize that the problem involves a quantum harmonic oscillator. The energy levels of a quantum harmonic oscillator are given by the formula: , where is the quantum number (starting from 0), is the reduced Planck's constant, and is the angular frequency of the oscillator.
Step 2: Calculate the angular frequency using the formula , where is the spring constant (2.0 N/m) and is the mass of the electron (approximately kg).
Step 3: Substitute the calculated value of into the energy formula for the quantum harmonic oscillator. For the first three energy levels, use , , and .
Step 4: For each energy level, calculate the corresponding energy using the formula . Remember that (reduced Planck's constant) is approximately J·s.
Step 5: Express the first three energy levels in terms of their values (symbolically or numerically, depending on the calculation). Ensure the units are consistent throughout the calculation, and verify the results for accuracy.

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Quantum Harmonic Oscillator
The quantum harmonic oscillator is a fundamental model in quantum mechanics that describes a particle subject to a restoring force proportional to its displacement from an equilibrium position. This model is crucial for understanding systems like electrons in potential wells, where the energy levels are quantized and can be calculated using specific formulas.
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Energy Levels
In quantum mechanics, energy levels refer to the discrete values of energy that a quantum system, such as an electron in a harmonic potential well, can occupy. For a harmonic oscillator, these energy levels are given by the formula E_n = (n + 1/2)ħω, where n is a non-negative integer, ħ is the reduced Planck's constant, and ω is the angular frequency of the oscillator.
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Intro to Energy & Types of Energy
Spring Constant and Angular Frequency
The spring constant (k) is a measure of the stiffness of a spring, and it plays a vital role in determining the angular frequency (ω) of a harmonic oscillator, given by ω = √(k/m), where m is the mass of the particle. In this context, knowing the spring constant allows us to calculate the angular frequency, which is essential for determining the energy levels of the electron in the harmonic potential well.
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