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Ch.8 - Basic Concepts of Chemical Bonding
Brown - Chemistry: The Central Science 14th Edition
Brown14th EditionChemistry: The Central ScienceISBN: 9780134414232당신이 사용하는 게 아니라요?교과서 변경
8장, 문제 41

Which of the following bonds are polar? (a) C—O, (b) Sl—F, (c) N—Cl, (d) C—Cl. Which is the more electronegative atom in each polar bond?

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insert step 1> Determine the electronegativity values of the elements involved in each bond. You can refer to a periodic table with electronegativity values for this purpose.
insert step 2> Compare the electronegativity values of the two atoms in each bond. A bond is considered polar if there is a significant difference in electronegativity between the two atoms.
insert step 3> For each bond, if the difference in electronegativity is greater than approximately 0.5, the bond is polar.
insert step 4> Identify the more electronegative atom in each polar bond. The more electronegative atom will attract the shared electrons more strongly, resulting in a partial negative charge.
insert step 5> List the polar bonds and indicate the more electronegative atom for each.

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주요 개념

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Electronegativity

Electronegativity is a measure of an atom's ability to attract and hold onto electrons in a chemical bond. It varies across the periodic table, with elements like fluorine being highly electronegative. In a bond between two different atoms, the atom with higher electronegativity will attract the shared electrons more strongly, leading to a polar bond.
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가이드 코스
02:10
Electronegativity Trends

Polar Bonds

A polar bond occurs when there is a significant difference in electronegativity between the two atoms involved in the bond. This difference causes an uneven distribution of electron density, resulting in a dipole moment where one end of the bond is slightly negative and the other slightly positive. Bonds are considered polar if the electronegativity difference is typically greater than 0.4.
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가이드 코스
02:38
Molecular Polarity

Dipole Moment

The dipole moment is a vector quantity that represents the separation of positive and negative charges in a polar bond. It is calculated as the product of the charge difference and the distance between the charges. A larger dipole moment indicates a stronger polarity, which can influence the physical properties of molecules, such as solubility and boiling points.
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