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Ch.10 - Gases
Brown - Chemistry: The Central Science 15th Edition
Brown15th EditionChemistry: The Central ScienceISBN: 9780137542970당신이 사용하는 게 아니라요?교과서 변경
10장, 문제 45a

In an experiment reported in the scientific literature, male cockroaches were made to run at different speeds on a miniature treadmill while their oxygen consumption was measured. In 1 h the average cockroach running at 0.08 km/h consumed 0.8 mL of O2 at 1 atm pressure and 24°C per gram of insect mass. a. How many moles of O2 would be consumed in 1 h by a 5.2-g cockroach moving at this speed?

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1. First, we need to understand that the given oxygen consumption is per gram of insect mass. So, for a 5.2-g cockroach, the total oxygen consumption would be 5.2 times the given rate. That is, 5.2 * 0.8 mL = 4.16 mL of O2.
2. Now, we need to convert this volume of O2 at the given conditions to moles. We can use the ideal gas law for this. The ideal gas law is PV = nRT, where P is the pressure, V is the volume, n is the number of moles, R is the ideal gas constant, and T is the temperature in Kelvin.
3. We know that at STP (Standard Temperature and Pressure, which is 0°C and 1 atm), 1 mole of any gas occupies 22.4 L. However, our conditions are not at STP. The temperature is 24°C, not 0°C. So, we need to adjust for this. We can convert the temperature to Kelvin by adding 273 to the Celsius temperature. So, 24°C = 297 K.
4. Now, we can rearrange the ideal gas law to solve for n (number of moles). The rearranged formula is n = PV/RT. We know that P = 1 atm, V = 4.16 mL (which we need to convert to L by dividing by 1000, so V = 0.00416 L), R = 0.0821 L.atm/K.mol (the value of R in these units), and T = 297 K.
5. Substitute these values into the formula to find the number of moles of O2 consumed by the cockroach in 1 hour.

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주요 개념

질문에 올바르게 답하기 위해 반드시 이해해야 하는 핵심 개념들은 다음과 같습니다.

Molar Volume of Gases

The molar volume of a gas at standard temperature and pressure (STP) is approximately 22.4 liters per mole. This concept is essential for converting the volume of gas consumed (in mL) into moles. In this case, knowing the volume of O2 consumed allows us to apply the ideal gas law or molar volume relationships to find the number of moles.
추천 영상:
가이드 코스
01:21
Standard Molar Volume

Stoichiometry

Stoichiometry involves the calculation of reactants and products in chemical reactions. In this context, it helps determine how the amount of oxygen consumed relates to the mass of the cockroach. By using the oxygen consumption rate per gram of insect mass, we can calculate the total oxygen consumed by the specific mass of the cockroach.
추천 영상:
가이드 코스
01:16
Stoichiometry Concept

Gas Laws

Gas laws describe the behavior of gases under various conditions of pressure, volume, and temperature. In this scenario, the ideal gas law (PV=nRT) can be applied to relate the pressure, volume, and temperature of the oxygen consumed. Understanding these relationships is crucial for accurately calculating the moles of O2 based on the experimental conditions provided.
추천 영상:
가이드 코스
01:43
Combined Gas Law
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교과서 질문

Many gases are shipped in high-pressure containers. Consider a steel tank whose volume is 55.0 gallons that contains O2 gas at a pressure of 16,500 kPa at 23°C. c. At what temperature would the pressure in the tank equal 150.0 atm?

교과서 질문

The physical fitness of athletes is measured by 'VO2 max,' which is the maximum volume of oxygen consumed by an individual during incremental exercise (for example, on a treadmill). An average male has a VO2 max of 45 mL O2/kg body mass/min, but a world-class male athlete can have a VO2 max reading of 88.0 mL O2/kg body mass/min. (a) Calculate the volume of oxygen, in mL, consumed in 1 hr by an average man who weighs 85 kg and has a VO2 max reading of 47.5 mL O2/kg body mass/min. (b) If this man lost 10 kg, exercised, and increased his VO2 max to 65.0 mL O2/kg body mass/min, how many mL of oxygen would he consume in 1 hr?

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교과서 질문

Many gases are shipped in high-pressure containers. Consider a steel tank whose volume is 55.0 gallons that contains O2 gas at a pressure of 16,500 kPa at 23°C. b. What volume would the gas occupy at STP?

교과서 질문

Many gases are shipped in high-pressure containers. Consider a steel tank whose volume is 55.0 gallons that contains O2 gas at a pressure of 16,500 kPa at 23°C. d. What would be the pressure of the gas, in kPa, if it were transferred to a container at 24°C whose volume is 55.0 L?

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교과서 질문

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교과서 질문

Rank the following gases from least dense to most dense at 1.00 atm and 298 K: CO, N2O, Cl2, HF.