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Chapter 14: Ethers, Epoxides, and Thioethers – Structure, Properties, and Reactivity

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Functional Groups

  • Assigning Degrees to Alkyl Halides
    01:30
  • Why we need functional groups.
    01:49
  • The difference between aldehydes and ketones.
    03:08

Williamson Ether Synthesis

  • The Mechanism of Williamson Ether Synthesis.
    03:50

Epoxidation

  • Halohydrins to epoxides via intramolecular SN2.
    02:26
  • General properties of epoxidation.
    02:19
  • The mechanism of how peroxy acids make epoxides.
    03:19

Epoxide Ring Opening

  • Base-Catalyzed Epoxide Ring-Opening
    04:44
  • Acid-Catalyzed Epoxide Ring-Opening
    04:34

Silyl Ether Protecting Groups

  • Mechanism of Silyl Ether Protecting Groups.
    07:16
  • Predict the product of the following reaction.
    03:37

Reactions of Thiols

  • The mechanism of Disulfide Synthesis.
    02:55
  • The mechanism of Sulfide Synthesis.
    03:21

Introduction to Conjugation

  • Conjugated states
    03:27
  • Definition of Conjugation
    05:29
  • Review of Common Resonance Structures
    04:50

Molecular Orbitals

  • Sigma bond vs. pi bond, which is stronger?
    03:25
  • What’s the difference between sigma and pi bonds?
    02:19
  • What’s the difference between atomic and molecular orbitals?
    11:25

Basics of Molecular Orbital Theory

  • Review of Atomic Orbitals
    16:
  • Review of Molecular Orbitals
    08:41