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Organic Chemistry Core Concepts: Structured Study Notes

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Alkane Nomenclature

  • Naming the root chain
    01:02
  • Provide the IUPAC name for the following alkane
    07:08
  • The different parts of an IUPAC name
    03:43

Cycloalkanes

  • Name the following alkane
    00:53
  • Determining Root Name
    00:18
  • Determining Root Name
    00:34

Cyclohexane – Chairs and Positions

  • What is a chair conformation?
    01:05
  • How chairs flip from one conformation to another
    02:22
  • How chairs flip from one conformation to another
    04:26

Chair Flip

  • The 3 important factors when drawing chairs
    05:12

Newman Projections – Conformational Energy

  • How to draw a Newman Projection Energy Diagram.
    07:27
  • How sigma bond rotation is visualized
    03:11
  • The energy states of 3 different Newman Projections.
    03:51

Carbocation Intermediates – Stability

  • Determining Carbocation Stability
    05:58
  • Predicting the most stable carbocation
    01:21

Stability of Alkenes

  • Heat of Combustion
    02:55
  • Understanding trends of alkene stability.
    04:28

Carbocation Intermediate – Rearrangements

  • Alkyl Shift
    03:43
  • Understanding why carbocations shift.
    00:47
  • Hydride Shift
    03:34

Markovnikov's Rule

  • Provide the mechanism
    01:26
  • How to add to asymmetrical double bonds.
    03:38

Weak Oxidative Cleavage

  • General properties of ozonolysis.
    06:30

Halogenation

  • Halogenation Mechanism
    03:45
  • General properties of halogenation.
    02:27

Epoxidation

  • Halohydrins to epoxides via intramolecular SN2.
    02:26
  • General properties of epoxidation.
    02:19
  • The mechanism of how peroxy acids make epoxides.
    03:19

Electrophilic Aromatic Substitution – General Mechanism

  • EAS General Mechanism
    06:52
  • EAS Review
    03:07

EAS-o, p-Major Products

  • Ortho, Para major products
    04:42

Four Tests of Aromaticity

  • Four tests
    10:23

Cahn-Ingold-Prelog Nomenclature

  • R and S Naming- Step 4
    03:07
  • Why stereoisomers need their own naming system.
    01:48
  • Determining Priorities
    01:19

Meso Compounds

  • Defining meso compounds.
    01:40
  • The 3 rules of meso compounds.
    04:10
  • Which of the following molecules are meso?
    03:44

Chirality

  • Drawing Mirror Images and Determining Chirality
    03:24
  • What is chirality?
    05:10
  • Drawing Mirror Images and Determining Chirality
    03:44

The SN1 Mechanism

  • Drawing the SN1 Mechanism
    10:49
  • Why highly substituted leaving groups favor SN1.
    01:13
  • Understanding the properties of SN1.
    08:16

The SN2 Mechanism

  • Ranking reactivity toward SN2
    04:03
  • Drawing the SN2 Mechanism
    08:33
  • Understanding the properties of SN2.
    11:57

E2 Mechanism

  • Understanding the properties of E2.
    04:42
  • Drawing the E2 Mechanism.
    09:36
  • Rank reactivity toward E2
    02:03

The E1 Mechanism

  • Understanding the properties of E1.
    03:32
  • Drawing the E1 Mechanism.
    08:09

Leaving Groups

  • Predict the best leaving group
    00:50
  • Predict the best leaving group
    01:12
  • Predict the best leaving group
    00:36

Nucleophiles and Basicity

  • Understanding the difference between basicity and nucleophilicity.
    06:21

Elimination and Zaitsev's Rule

  • Hofmann product
    02:39
  • Defining Zaitsev’s Rule
    01:18
  • Zaitsev product
    07:01

Intro to Redox

  • Distinguishing between Oxidation and Reduction
    00:54
  • Distinguishing between Oxidation and Reduction
    01:18
  • Distinguishing between Oxidation and Reduction
    00:54

Leaving Group Conversions - SOCl2 and PBr3

  • Predict the mechanism of PBr3, and draw the final product.
    06:01
  • Learning the mechanism of SOCl2.
    07:18

Acid-Catalyzed Dehydration

  • Dehydration of 1° alcohols:The E2 Mechanism
    05:20
  • An extra note of caution with 1° alcohols.
    01:06
  • General features of acid-catalyzed dehydration.
    06:01

Williamson Ether Synthesis

  • The Mechanism of Williamson Ether Synthesis.
    03:50

Preparation of Organometallics

  • Ruining Organometallics
    02:50
  • General Reaction
    12:21

Reactions of Organometallics

  • Reactions of Organometallics
    13:40

Acetals as Protecting Groups

  • Protecting Groups
    02:44
  • Acetal Protecting Group
    04:29

Nucleophilic Acyl Substitution – The Three Rules

  • NAS - The Three Rules
    09:32

Fischer Esterification – Mechanism

  • General Mechanism
    04:08
  • General Reaction
    01:08