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Properties of Water and Acid-Base Chemistry in Biology

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Concept 3.2: Cohesive Properties of Water

1. Cohesion and Adhesion of Water

Water molecules exhibit unique cohesive and adhesive properties due to their molecular structure and hydrogen bonding.

  • Cohesion: Water molecules are attracted to each other via hydrogen bonds, resulting in high surface tension.

  • Adhesion: Water molecules can also be attracted to other substances, such as glass, which is important for processes like capillary action.

  • Example: Water droplets forming on a leaf due to cohesion; water climbing up a thin tube due to adhesion.

2. Temperature and Thermal Energy

Water has a high capacity to absorb and retain heat, which is crucial for maintaining stable temperatures in biological systems.

  • Thermal energy: The kinetic energy of molecules; higher thermal energy means higher temperature.

  • Specific heat: Water can absorb a large amount of heat with only a small increase in temperature.

  • Calorie: The amount of energy needed to raise 1 gram of water by 1 degree Celsius.

  • High heat of vaporization: Water requires significant energy to change from liquid to gas, helping organisms cool down via evaporation.

  • Expansion upon freezing: Water forms a crystalline structure when frozen, making ice less dense than liquid water.

  • Hydrogen bonds: These bonds are not broken when water freezes, contributing to the unique properties of ice.

3. Water as a Solvent

Water's polarity makes it an excellent solvent, capable of dissolving a wide variety of substances.

  • Solution: A homogeneous mixture of two or more substances.

  • Solvent: The substance that dissolves the solute (water is often called the "universal solvent").

  • Solute: The substance that is dissolved.

  • Polarity: Water's polar nature allows it to dissolve ionic and polar compounds effectively.

  • Example: Table salt (NaCl) dissolving in water due to the attraction between water molecules and the ions.

Concept 3.3: Acidic and Basic Conditions Affect Living Organisms

1. Water and pH

The pH of a solution is determined by the concentration of hydrogen ions (H+), which affects biological processes.

  • Water autoionization: Water molecules can dissociate into H+ and OH- ions.

  • pH scale: Measures the concentration of H+ ions; lower pH means higher acidity.

  • Acid: A substance that increases the H+ concentration in a solution.

  • Base: A substance that decreases the H+ concentration, often by increasing OH-.

  • Strong acids and bases: Dissociate completely in water.

  • Weak acids and bases: Dissociate only partially.

2. Buffers and Buffer Solutions

Buffers help maintain stable pH in biological systems by neutralizing excess acids or bases.

  • Buffer: A solution that resists changes in pH when acids or bases are added.

  • Buffer solution: Typically consists of a weak acid and its conjugate base.

  • Example: Blood contains buffers to maintain a stable pH necessary for physiological functions.

3. Buffer Action (Table)

The following table illustrates how buffers work to maintain pH stability when acids or bases are added:

Condition

Buffer Action

Result

Addition of OH-

Weak acid neutralizes added base, forming conjugate base

pH remains stable

Addition of H3O+

Conjugate base neutralizes added acid, forming weak acid

pH remains stable

Additional info: Buffer systems are essential in biological fluids, such as blood, to prevent harmful changes in pH.

4. Key Equations

  • Water dissociation:

  • pH calculation:

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