Which, if any, of the following statements are true? (a) The stronger the base, the smaller the pKb. (b) The stronger the base, the larger the pKb. (c) The stronger the base, the smaller the Kb. (d) The stronger the base, the larger the Kb. (e) The stronger the base, the smaller the pKa of its conjugate acid. (f) The stronger the base, the larger the pKa of its conjugate acid.
Ch.16 - Acid-Base Equilibria
16장, 문제 99d
Indicate whether each of the following statements is correct or incorrect. (d) K+ ion is acidic in water because it causes hydrating water molecules to become more acidic.
검증된 단계별 안내1
Understand the nature of the K+ ion: Potassium ion (K+) is a cation formed when potassium loses one electron.
Consider the concept of acidity in water: A species is considered acidic if it can donate a proton (H+) to water, increasing the concentration of H3O+ ions.
Evaluate the interaction of K+ with water: K+ is a large, monovalent cation with a low charge density, meaning it does not significantly polarize water molecules.
Analyze the effect of K+ on water acidity: Since K+ does not polarize water molecules effectively, it does not increase the acidity of water by donating protons or causing water to release protons.
Conclude the statement's correctness: Based on the analysis, determine whether the statement about K+ ion being acidic in water is correct or incorrect.

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Acidity and Basicity
Acidity refers to the ability of a substance to donate protons (H+) in a solution, while basicity refers to the ability to accept protons. In aqueous solutions, acids increase the concentration of H+ ions, which lowers the pH, making the solution more acidic. Understanding these definitions is crucial for evaluating the behavior of ions like K+ in water.
추천 영상:
가이드 코스
Anion Acidity and Basicity
Hydration of Ions
When ions dissolve in water, they interact with water molecules, forming a hydration shell. This process can influence the properties of the solution, including its acidity. However, the K+ ion, being a cation of a strong base (KOH), does not significantly affect the pH of water, as it does not lead to an increase in H+ concentration.
추천 영상:
가이드 코스
Ionic Hydrates Naming
Strong vs. Weak Acids and Bases
Strong acids and bases completely dissociate in water, while weak acids and bases do not. The K+ ion originates from potassium hydroxide, a strong base, which means it does not contribute to acidity in solution. Recognizing the strength of acids and bases is essential for determining the behavior of ions in aqueous environments.
추천 영상:
가이드 코스
Strong vs Weak Bases
관련 실천
교과서 질문
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교과서 질문
Indicate whether each of the following statements is correct or incorrect. (c) Conjugate acids of weak bases produce more acidic solutions than conjugate acids of strong bases.
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A solution is made by adding 0.300 g Ca1OH221s2, 50.0 mL of 1.40 M HNO3, and enough water to make a final volume of 75.0 mL. Assuming that all of the solid dissolves, what is the pH of the final solution?
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교과서 질문
Salts containing the phosphate ion are added to municipal
water supplies to prevent the corrosion of lead pipes. (a) Based
on the pKa values for phosphoric acid 1pKa1 = 7.5 * 10 - 3,
pKa2 = 6.2 * 10 - 8, pKa3 = 4.2 * 10 - 132 what is the Kb
value for the PO43 - ion?
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교과서 질문
Which member of each pair produces the more acidic aqueous solution: (a) ZnBr2 or CdCl2 (b) CuCl or Cu(NO3)2 (c) Ca(NO3)2 or NiBr2
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