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Ch.8 - Basic Concepts of Chemical Bonding
Brown - Chemistry: The Central Science 14th Edition
Brown14th EditionChemistry: The Central ScienceISBN: 9780134414232당신이 사용하는 게 아니라요?교과서 변경
8장, 문제 67a

There are many Lewis structures you could draw for sulfuric acid, H2SO4 (each H is bonded to an O). (a) What Lewis structure(s) would you draw to satisfy the octet rule?

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Identify the total number of valence electrons available: Hydrogen (H) has 1 valence electron, Oxygen (O) has 6, and Sulfur (S) has 6. Calculate the total for H2SO4.
Determine the central atom: Sulfur (S) is less electronegative than Oxygen (O) and can form more bonds, so it will be the central atom.
Connect the atoms: Place Sulfur in the center, connect each Oxygen to Sulfur, and then attach each Hydrogen to an Oxygen.
Distribute the remaining electrons to satisfy the octet rule: Start by completing the octets of the outer atoms (Oxygens), then place any remaining electrons on the central atom (Sulfur).
Consider resonance structures: Check if there are any possible resonance structures by moving electrons to form double bonds, ensuring that the octet rule is satisfied for each atom.

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Lewis Structures

Lewis structures are diagrams that represent the bonding between atoms in a molecule and the lone pairs of electrons that may exist. They use dots to represent valence electrons and lines to represent bonds between atoms. Understanding how to draw Lewis structures is essential for visualizing molecular geometry and predicting the behavior of molecules.
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Lewis Dot Structures: Ions

Octet Rule

The octet rule is a chemical rule of thumb that states atoms tend to bond in such a way that they each have eight electrons in their valence shell, achieving a stable electron configuration similar to that of noble gases. This rule helps predict the arrangement of electrons in molecules and is particularly useful when drawing Lewis structures for compounds like sulfuric acid.
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Resonance Structures

Resonance structures are different Lewis structures that represent the same molecule, where the actual structure is a hybrid of these forms. In the case of sulfuric acid, multiple resonance structures can be drawn to depict the delocalization of electrons, particularly in the sulfate ion. Recognizing resonance is crucial for accurately representing the electron distribution in complex molecules.
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Resonance Structures
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교과서 질문

(a) Describe the molecule xenon trioxide, XeO3, using four possible Lewis structures, one each with zero, one, two, or three Xe¬O double bonds. (b) Do any of these resonance structures satisfy the octet rule for every atom in the molecule? (c) Do any of the four Lewis structures have multiple resonance structures? If so, how many resonance structures do you find? (d) Which of the Lewis structures in part (a) yields the most favorable formal charges for the molecule?

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교과서 질문

There are many Lewis structures you could draw for sulfuric acid, H2SO4 (each H is bonded to an O). (b) What Lewis structure(s) would you draw to minimize formal charge?

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교과서 질문

Some chemists believe that satisfaction of the octet rule should be the top criterion for choosing the dominant Lewis structure of a molecule or ion. Other chemists believe that achieving the best formal charges should be the top criterion. Consider the dihydrogen phosphate ion, H2PO4-, in which the H atoms are bonded to O atoms. (a) What is the predicted dominant Lewis structure if satisfying the octet rule is the top criterion?

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교과서 질문

Some chemists believe that satisfaction of the octet rule should be the top criterion for choosing the dominant Lewis structure of a molecule or ion. Other chemists believe that achieving the best formal charges should be the top criterion. Consider the dihydrogen phosphate ion, H2PO4-, in which the H atoms are bonded to O atoms. (b) What is the predicted dominant Lewis structure if achieving the best formal charges is the top criterion?

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교과서 질문

In the vapor phase, BeCl2 exists as a discrete molecule. (b) What other resonance structures are possible that satisfy the octet rule?

교과서 질문

In the vapor phase, BeCl2 exists as a discrete molecule. (c) On the basis of the formal charges, which Lewis structure is expected to be dominant for BeCl2?

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