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Ch.4 - Reactions in Aqueous Solution
McMurry - Chemistry 8th Edition
McMurry8th EditionChemistryISBN: 9781292336145당신이 사용하는 게 아니라요?교과서 변경
4장, 문제 108d

Assign oxidation numbers to each element in the following compounds. (d) CH2Cl2

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Step 1: Understand that the sum of oxidation numbers in a neutral compound is zero.
Step 2: Assign the oxidation number of hydrogen (H) as +1. Since there are two hydrogen atoms, their total contribution is +2.
Step 3: Assign the oxidation number of chlorine (Cl) as -1. Since there are two chlorine atoms, their total contribution is -2.
Step 4: Let the oxidation number of carbon (C) be x. Set up the equation based on the sum of oxidation numbers: x + 2(+1) + 2(-1) = 0.
Step 5: Solve the equation for x to find the oxidation number of carbon.

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주요 개념

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Oxidation Numbers

Oxidation numbers are a way to keep track of electrons in chemical compounds. They indicate the degree of oxidation of an atom in a molecule, helping to identify how many electrons an atom has gained, lost, or shared. The rules for assigning oxidation numbers include that the oxidation number of an element in its elemental form is zero, and for monoatomic ions, it equals the charge of the ion.
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Oxidation Numbers

Common Oxidation States

Certain elements have common oxidation states that are frequently encountered in compounds. For example, hydrogen typically has an oxidation number of +1, while chlorine usually has an oxidation number of -1. Understanding these common states is essential for accurately assigning oxidation numbers in more complex molecules.
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Common Ion Effect

Sum of Oxidation Numbers

The sum of the oxidation numbers in a neutral compound must equal zero. This principle is crucial when determining the oxidation numbers of individual elements within a compound. For example, in CH2Cl2, the total oxidation number must balance out to zero, guiding the assignment of oxidation states to carbon, hydrogen, and chlorine.
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Oxidation Numbers