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Ch.16 - Acids and Bases
Tro - Chemistry: A Molecular Approach 4th Edition
Tro4th EditionChemistry: A Molecular ApproachISBN: 9780134112831당신이 사용하는 게 아니라요?교과서 변경
16장, 문제 42c

Classify each acid as strong or weak. If the acid is weak, write an expression for the acid ionization constant (Ka). c. H2SO4

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1
Identify the acid in question: \( \text{H}_2\text{SO}_4 \) (sulfuric acid).
Recall that \( \text{H}_2\text{SO}_4 \) is a strong acid, meaning it completely dissociates in water.
Understand that strong acids do not have an acid ionization constant (\( K_a \)) because they fully dissociate.
Note that the first dissociation of \( \text{H}_2\text{SO}_4 \) is complete: \( \text{H}_2\text{SO}_4 \rightarrow \text{H}^+ + \text{HSO}_4^- \).
Recognize that the second dissociation of \( \text{HSO}_4^- \) is weak: \( \text{HSO}_4^- \rightleftharpoons \text{H}^+ + \text{SO}_4^{2-} \), and for this, you can write \( K_a = \frac{[\text{H}^+][\text{SO}_4^{2-}]}{[\text{HSO}_4^-]} \).

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주요 개념

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Strong and Weak Acids

Strong acids completely dissociate in water, releasing all their hydrogen ions (H+), while weak acids only partially dissociate. This distinction is crucial for understanding acid behavior in solution, as strong acids have a high concentration of H+ ions, leading to a lower pH, whereas weak acids result in a higher pH due to their incomplete dissociation.
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Weak Acid-Strong Base Titration Curve

Acid Ionization Constant (Ka)

The acid ionization constant (Ka) quantifies the strength of a weak acid by measuring the extent of its dissociation in water. It is defined by the equilibrium expression: Ka = [H+][A-]/[HA], where [H+] is the concentration of hydrogen ions, [A-] is the concentration of the conjugate base, and [HA] is the concentration of the undissociated acid. A larger Ka value indicates a stronger weak acid.
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03:50
Characteristics of Ka and Kb

H2SO4 as a Strong Acid

H2SO4, sulfuric acid, is classified as a strong acid because it completely dissociates in its first ionization step, producing H+ and HSO4-. Although HSO4- can act as a weak acid in its second ionization, the first dissociation is what primarily characterizes H2SO4 as a strong acid, making it essential to recognize its behavior in acid-base reactions.
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01:09
Strong Acid-Strong Base Titration