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Ch.5 - Gases
Tro - Chemistry: A Molecular Approach 4th Edition
Tro4th EditionChemistry: A Molecular ApproachISBN: 9780134112831당신이 사용하는 게 아니라요?교과서 변경
5장, 문제 80

Carbon monoxide gas reacts with hydrogen gas to form methanol. CO(g) + 2 H2(g) → CH3OH(g) A 1.50-L reaction vessel, initially at 305 K, contains carbon monoxide gas at a partial pressure of 232 mmHg and hydrogen gas at a partial pressure of 397 mmHg. Identify the limiting reactant. Determine the theoretical yield of methanol in grams.

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1
Write the balanced chemical equation for the reaction: \( \text{CO(g)} + 2 \text{H}_2\text{(g)} \rightarrow \text{CH}_3\text{OH(g)} \).
Use the ideal gas law \( PV = nRT \) to calculate the number of moles of CO and \( \text{H}_2 \) in the reaction vessel. Assume \( R = 0.0821 \text{ L atm mol}^{-1} \text{ K}^{-1} \) and convert pressures from mmHg to atm.
Determine the limiting reactant by comparing the mole ratio of CO to \( \text{H}_2 \) with the stoichiometric ratio from the balanced equation.
Calculate the theoretical yield of methanol by using the moles of the limiting reactant and the stoichiometry of the reaction to find the moles of \( \text{CH}_3\text{OH} \) produced.
Convert the moles of \( \text{CH}_3\text{OH} \) to grams using its molar mass (32.04 g/mol).

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주요 개념

질문에 올바르게 답하기 위해 반드시 이해해야 하는 핵심 개념들은 다음과 같습니다.

Limiting Reactant

The limiting reactant is the substance that is completely consumed first in a chemical reaction, thus determining the maximum amount of product that can be formed. To identify it, one must compare the mole ratios of the reactants based on the balanced chemical equation. The reactant that produces the least amount of product is the limiting reactant.
추천 영상:
가이드 코스
01:30
Limiting Reagent Concept

Partial Pressure

Partial pressure is the pressure exerted by a single component of a gas mixture. According to Dalton's Law of Partial Pressures, the total pressure of a gas mixture is the sum of the partial pressures of each individual gas. This concept is crucial for calculating the number of moles of each reactant present in the reaction vessel.
추천 영상:
가이드 코스
00:48
Partial Pressure Calculation

Theoretical Yield

The theoretical yield is the maximum amount of product that can be generated from a given amount of reactants, assuming complete conversion and no losses. It is calculated using stoichiometry based on the limiting reactant. The theoretical yield is typically expressed in grams and is essential for evaluating the efficiency of a chemical reaction.
추천 영상:
가이드 코스
03:09
Percent Yield in Reactions
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Ozone is depleted in the stratosphere by chlorine from CF3Cl according to this set of equations:

CF3Cl + UV light → CF3 + Cl

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Chlorine gas reacts with fluorine gas to form chlorine trifluoride. Cl2(g) + 3 F2(g) → 2 ClF3(g) A 2.00-L reaction vessel, initially at 298 K, contains chlorine gas at a partial pressure of 337 mmHg and fluorine gas at a partial pressure of 729 mmHg. Identify the limiting reactant. Determine the theoretical yield of ClF3 in grams.

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