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Ch.20 - Electrochemistry
Tro - Chemistry: A Molecular Approach 5th Edition
Tro5th EditionChemistry: A Molecular ApproachISBN: 9780134874371당신이 사용하는 게 아니라요?교과서 변경
20장, 문제 60

Determine whether or not each metal dissolves in 1 M HIO3. For those metals that do dissolve, write a balanced redox equation for the reaction that occurs. a. Au b. Cr

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1
Identify the oxidation states and properties of the reactants. Gold (Au) is in its elemental form with an oxidation state of 0, and in HIO3, iodine typically has an oxidation state of +5.
Determine the potential for Au to be oxidized. Since Au is a noble metal, it is less reactive and has a higher reduction potential, meaning it is less likely to lose electrons and oxidize under normal conditions.
Consult the electrochemical series to compare the reduction potential of Au and the oxidizing power of HIO3. If the reduction potential of Au is higher than the oxidation potential of HIO3, Au will not dissolve.
If Au can be oxidized by HIO3, write the half-reactions for each species. For Au, the oxidation half-reaction would be Au → Au^3+ + 3e^-. For HIO3, the reduction half-reaction would involve the reduction of iodine.
Combine the half-reactions to form a balanced redox equation ensuring that the number of electrons lost in the oxidation half-reaction equals the number of electrons gained in the reduction half-reaction. Adjust coefficients as necessary to balance atoms and charges.

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주요 개념

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Redox Reactions

Redox reactions involve the transfer of electrons between two species, resulting in changes in oxidation states. In these reactions, one species is oxidized (loses electrons) while another is reduced (gains electrons). Understanding redox processes is crucial for predicting how metals will react with acids, such as HIO3, and for writing balanced chemical equations.
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Identifying Redox Reactions

Metal Reactivity

The reactivity of metals varies significantly, influencing their ability to dissolve in acids. Noble metals like gold (Au) are less reactive and often do not dissolve in dilute acids, while more reactive metals can readily react with acids to form metal ions. Knowing the position of metals in the reactivity series helps in predicting their behavior in acidic solutions.
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Transition Metals

Balanced Chemical Equations

A balanced chemical equation represents a chemical reaction with equal numbers of each type of atom on both sides of the equation. Balancing equations is essential for accurately depicting the stoichiometry of reactions, including redox reactions involving metals and acids. This ensures that the conservation of mass is maintained and allows for the calculation of reactants and products.
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01:32
Balancing Chemical Equations