The activation barrier for the hydrolysis of sucrose into glucose and fructose is 108 kJ/mol. If an enzyme increases the rate of the hydrolysis reaction by a factor of 1 million, how much lower must the activation barrier be when sucrose is in the active site of the enzyme? (Assume that the frequency factors for the catalyzed and uncatalyzed reactions are identical and a temperature of 25 °C.)
Ch.15 - Chemical Kinetics

15장, 문제 89a
The tabulated data were collected for this reaction at 500 °C: CH3CN(g) → CH3NC( g) a. Determine the order of the reaction and the value of the rate constant at this temperature.
검증된 단계별 안내1
Step 1: Understand the problem. We need to determine the order of the reaction and the rate constant for the given reaction at 500 °C.
Step 2: Analyze the data. Look at the concentration of CH3CN over time to see how it changes. This will help us determine the order of the reaction.
Step 3: Determine the reaction order. Use the method of initial rates or plot concentration vs. time data to find if the reaction is zero, first, or second order.
Step 4: Calculate the rate constant. Once the order is known, use the appropriate rate law equation to calculate the rate constant, k.
Step 5: Verify your results. Check if the calculated rate constant and reaction order are consistent with the data provided.

비슷한 문제에 대한 검증된 영상 답변:
이 영상 해법은 위 문제에 도움이 된다고 튜터들이 추천한 것입니다.
영상 길이:
5m주요 개념
질문에 올바르게 답하기 위해 반드시 이해해야 하는 핵심 개념들은 다음과 같습니다.
Reaction Order
The order of a reaction refers to the power to which the concentration of a reactant is raised in the rate law. It indicates how the rate of reaction depends on the concentration of reactants. For example, a first-order reaction has a rate that is directly proportional to the concentration of one reactant, while a second-order reaction depends on the square of the concentration of one reactant or the product of the concentrations of two reactants.
추천 영상:
가이드 코스
Average Bond Order
Rate Constant (k)
The rate constant, denoted as 'k', is a proportionality factor in the rate law that relates the rate of a reaction to the concentrations of the reactants. It is specific to a given reaction at a particular temperature and provides insight into the speed of the reaction. The value of 'k' can be determined experimentally and varies with temperature, reflecting the energy barrier that must be overcome for the reaction to proceed.
추천 영상:
가이드 코스
Equilibrium Constant K
Arrhenius Equation
The Arrhenius equation describes how the rate constant 'k' changes with temperature. It is expressed as k = A * e^(-Ea/RT), where 'A' is the pre-exponential factor, 'Ea' is the activation energy, 'R' is the universal gas constant, and 'T' is the temperature in Kelvin. This equation highlights the exponential relationship between temperature and reaction rate, indicating that higher temperatures generally lead to increased reaction rates due to more molecules having sufficient energy to overcome the activation energy barrier.
추천 영상:
가이드 코스
Arrhenius Equation
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The tabulated data were collected for this reaction at 500 °C: CH3CN(g) → CH3NC( g) b. What is the half-life for this reaction (at the initial concentration)?
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The tabulated data were collected for this reaction at a certain temperature: X2Y → 2 X + Y a. Determine the order of the reaction and the value of the rate constant at this temperature.
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