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문제 80h
A 25.0-mL sample of 0.125 M pyridine is titrated with 0.100 M HCl. Calculate the pH at each volume of added acid: 0 mL, 10 mL, 20 mL, equivalence point, one-half equivalence point, 40 mL, 50 mL. Sketch the titration curve.
문제 81a
Consider the titration curves (labeled a and b) for two weak acids, both titrated with 0.100 M NaOH.
(i) Which acid solution is more concentrated?
문제 81b
Consider the titration curves (labeled a and b) for two weak acids, both titrated with 0.100 M NaOH.
(ii) Which acid has the larger Ka?
문제 82
Consider the titration curves (labeled a and b) for two weak bases, both titrated with 0.100 M HCl. (a)
(b)
(ii) Which base has the larger Kb?
문제 83
A 0.229-g sample of an unknown monoprotic acid is titrated with 0.112 M NaOH. The resulting titration curve is shown here. Determine the molar mass and pKa of the acid.
- Is a 0.446-g sample of an unknown monoprotic acid titrated with 0.105 M KOH resulting in a titration curve sufficient to determine the molar mass and pKa of the acid?
문제 84
문제 85
A 20.0-mL sample of 0.115 M sulfurous acid (H2SO3) solution is titrated with 0.1014 M KOH. At what added volume of base solution does each equivalence point occur?
문제 87
Methyl red has a pKa of 5.0 and is red in its acid form and yellow in its basic form. If several drops of this indicator are placed in a 25.0-mL sample of 0.100 M HCl, what color will the solution appear? If 0.100 M NaOH is slowly added to the HCl sample, in what pH range will the indicator change color?
- Phenolphthalein has a pKa of 9.7. It is colorless in its acid form and pink in its basic form. For each of the following pH values, determine whether [In-] > [HIn] and predict the color of a phenolphthalein solution: a. pH = 2.0 b. pH = 5.0 c. pH = 8.0 d. pH = 11.0
문제 88
문제 89
Referring to Table 18.1, pick an indicator for use in the titration of each acid with a strong base. a. HF
문제 90a
Referring to Table 17.1, pick an indicator for use in the titration of each base with a strong acid. a. CH3NH2
문제 91a
Write balanced equations and expressions for Ksp for the dissolution of each ionic compound. a. BaSO4
문제 91b
Write balanced equations and expressions for Ksp for the dissolution of each ionic compound. b. PbBr2
문제 91c
Write balanced equations and expressions for Ksp for the dissolution of each ionic compound. c. Ag2CrO4
문제 93a
Refer to the Ksp values in Table 18.2 to calculate the molar solubility of each compound in pure water. a. AgBr
문제 95a
Use the given molar solubilities in pure water to calculate Ksp for each compound. a. MX; molar solubility = 3.27⨉10-11 M
문제 95b
Use the given molar solubilities in pure water to calculate Ksp for each compound. b. PbF2; molar solubility = 5.63⨉10-3 M c. MgF2; molar solubility = 2.65⨉10-4 M
문제 96a
Use the given molar solubilities in pure water to calculate Ksp for each compound. a. BaCrO4; molar solubility = 1.08⨉10-5 M
문제 96b
Use the given molar solubilities in pure water to calculate Ksp for each compound. b. Ag2SO3; molar solubility = 1.55⨉10-5 M c. Pd(SCN)2; molar solubility = 2.22⨉10-8 M
문제 97
Two compounds with general formulas AX and AX2 have Ksp = 1.5⨉10-5. Which of the two compounds has the higher molar solubility?
문제 98
Consider the compounds with the generic formulas listed and their corresponding molar solubilities in pure water. Which compound has the smallest value of Ksp? a. AX; molar solubility = 1.35⨉10-4 M b. AX2; molar solubility = 2.25⨉10-4 M c. A2X; molar solubility = 1.75⨉10-4 M
문제 100
The solubility of copper(I) chloride is 3.91 mg per 100.0 mL of solution. Calculate Ksp for CuCl.
문제 101a
Calculate the molar solubility of barium fluoride in each liquid or solution. a. pure water
문제 101b
Calculate the molar solubility of barium fluoride in each liquid or solution. b. 0.10 M Ba(NO3)2
문제 101c
Calculate the molar solubility of barium fluoride in each liquid or solution. c. 0.15 M NaF
문제 102b
Calculate the molar solubility of MX (Ksp = 1.27⨉10-36) in each liquid or solution. b. 0.25 M MCl2
문제 102c
Calculate the molar solubility of MX (Ksp = 1.27⨉10-36) in each liquid or solution. c. 0.20 M Na2X
문제 103a
Calculate the molar solubility of calcium hydroxide in a solution buffered at each pH. a. pH = 4
문제 103b
Calculate the molar solubility of calcium hydroxide in a solution buffered at each pH. b. pH = 7
문제 103c
Calculate the molar solubility of calcium hydroxide in a solution buffered at each pH. c. pH = 9