What is the balanced half reaction that occurs at the anode in the overall cell reaction of a voltaic cell? 3 MnO4–(aq) + 5 Fe(s) → 3 Mn2+(aq) + 5 Fe3+(aq)
Identify the overall cell reaction given: 3 MnO4–(aq) + 5 Fe(s) → 3 Mn2+(aq) + 5 Fe3+(aq). This reaction involves both oxidation and reduction processes.
Determine the oxidation process occurring at the anode. In a voltaic cell, oxidation occurs at the anode, where electrons are lost.
Examine the species involved in the oxidation process. Here, Fe(s) is oxidized to Fe3+(aq), indicating that iron is losing electrons.
Write the half-reaction for the oxidation of iron. Start with the reactant Fe(s) and show the loss of electrons to form Fe3+(aq).
Balance the half-reaction for charge and mass. Ensure that the number of electrons lost equals the change in oxidation state from Fe(s) to Fe3+(aq), which is 3 electrons.