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Ch.10 Acids and Bases and Equilibrium
Timberlake - Chemistry: An Introduction to General, Organic, and Biological Chemistry 14th Edition
Timberlake14th EditionChemistry: An Introduction to General, Organic, and Biological ChemistryISBN: 9781292472249당신이 사용하는 게 아니라요?교과서 변경
10장, 문제 27

In an acidic solution, how does the concentration of H3O+ compare to the concentration of OH-?

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Understand that in any aqueous solution, the concentrations of H₃O⁺ (hydronium ions) and OH⁻ (hydroxide ions) are related by the ion-product constant for water, Kw, which is 1.0 × 10⁻¹⁴ at 25°C. This relationship is expressed as: Kw = [H3O+] × [OH].
Recognize that an acidic solution is defined as one where the concentration of H₃O⁺ is greater than the concentration of OH⁻. This means: [H3O+] > [OH].
Recall that the pH of a solution is a measure of its acidity and is calculated using the formula: pH = −log[H3O+]. For an acidic solution, the pH is less than 7.
Use the relationship between pH and pOH, which is given by: pH + pOH = 14. In an acidic solution, since the pH is less than 7, the pOH will be greater than 7, indicating a lower concentration of OH⁻.
Conclude that in an acidic solution, the concentration of H₃O⁺ is higher than the concentration of OH⁻, and this imbalance is what defines the solution as acidic.

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Acidic Solutions

An acidic solution is characterized by a higher concentration of hydronium ions (H₃O⁺) compared to hydroxide ions (OH⁻). This imbalance results in a pH value less than 7, indicating acidity. In such solutions, the presence of H₃O⁺ ions is what defines the solution as acidic, affecting various chemical reactions and properties.
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pH Scale

The pH scale quantifies the acidity or basicity of a solution, ranging from 0 to 14. A pH less than 7 indicates an acidic solution, where the concentration of H₃O⁺ is greater than that of OH⁻. Each unit change in pH represents a tenfold change in H₃O⁺ concentration, making it a crucial tool for understanding the nature of solutions.
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Ion Product of Water

The ion product of water (Kw) is the equilibrium constant for the self-ionization of water, defined as Kw = [H₃O⁺][OH⁻] = 1.0 x 10⁻¹⁴ at 25°C. In acidic solutions, as the concentration of H₃O⁺ increases, the concentration of OH⁻ must decrease to maintain this constant. This relationship is fundamental in determining the balance of ions in any aqueous solution.
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가이드 코스
01:37
Solubility Product Constant (Ksp) Concept 2