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Advanced Reactions of Alkenes: Mechanisms, Regiochemistry, and Stereochemistry
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Overview of Chemical Reactions
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01:34
Recognizing Substitution Reactions.
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02:43
Recognizing Acid-Base Reactions.
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00:40
Recognizing Elimination Reactions.
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Reaction Mechanism
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02:39
How to tell if charged molecules will react as nucleophiles or electrophiles.
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01:49
Nucleophile or Electrophile
Johnny Betancourt
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39
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11
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02:48
How to tell if uncharged molecules will react as nucleophiles or electrophiles.
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Markovnikov
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01:26
Provide the mechanism
Johnny Betancourt
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03:38
How to add to asymmetrical double bonds.
Johnny Betancourt
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69
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19
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Carbocation Intermediates – Stability
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05:58
Determining Carbocation Stability
Johnny Betancourt
5202
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25
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12
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01:21
Predicting the most stable carbocation
Johnny Betancourt
4280
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53
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17
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Carbocation Intermediate Rearrangements
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03:43
Alkyl Shift
Johnny Betancourt
4345
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42
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13
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00:47
Understanding why carbocations shift.
Johnny Betancourt
5202
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31
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5
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03:34
Hydride Shift
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4732
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Oxymercuration
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09:01
Acid-catalyzed oxymercuration-reduction mechanism
Johnny Betancourt
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05:
General properties of oxymercuration-reduction.
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5723
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16
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Reducing Agent
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00:15
Intro
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09:28
Reducing Agents
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Hydroboration
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06:38
General properties of hydroboration-oxidation.
Johnny Betancourt
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06:14
Acid-catalyzed hydroboration-oxidation mechanism
Johnny Betancourt
5284
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41
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21
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Hydroboration
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06:38
General properties of hydroboration-oxidation.
Johnny Betancourt
6010
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59
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06:14
Acid-catalyzed hydroboration-oxidation mechanism
Johnny Betancourt
5284
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41
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21
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Oxidizing and Reducing Agents
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00:54
Distinguishing between Oxidation and Reduction
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01:18
Distinguishing between Oxidation and Reduction
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27
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00:54
Distinguishing between Oxidation and Reduction
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Carbene
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Reaction with a simple carbene.
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03:01
Reaction with diazomethane and light or heat.
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2837
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03:04
Reaction with chloroform (CHCl3) and tert-butoxide.
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