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Alkenes and Alkynes: Structure, Reactions, and Stereochemistry

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Degrees of Unsaturation

  • Is the following molecule saturated?
    00:30
  • What is the IHD of the following molecule?
    00:45
  • What index of hydrogen deficiency is.
    01:15

Hybridization

  • How carbon creates 4 partially-filled orbitals.
    02:53
  • Bond sites, hybridization, and intermediate orbitals
    04:58
  • Introduction to the reactive intermediates.
    02:47

Cis vs Trans

  • Why we need to use the E/Z naming system
    02:07
  • What does E and Z stand for?
    00:50
  • How to name different types of double bonds or rings
    04:28

Alkene Stability

  • Heat of Combustion
    02:55
  • Understanding trends of alkene stability.
    04:28

Addition Reaction

  • Provide the mechanism
    01:15
  • Features of Addition Mechanisms.
    05:39

Hydrohalogenation

  • General properties of hydrohalogenation.
    04:07
  • Provide the mechanism
    02:24

Anti Markovnikov Addition of Br

  • Provide the complete mechanism for the following radical hydrohalogenation.
    02:53
  • How Radical Hydrohalogenation is different from typical Hydrohalogenation.
    07:13
  • Overview of Hydrohalogention.
    01:18

Acid-Catalyzed Hydration

  • General properties of acid-catalyzed hydration.
    06:32
  • Acid-catalyzed hydration mechanism
    06:34

Hydroboration

  • General properties of hydroboration-oxidation.
    06:38
  • Acid-catalyzed hydroboration-oxidation mechanism
    06:14

Alkyne Hydration

  • Vinyl alcohols yield tautomers.
    03:51
  • Markovnikov addition of alcohols yields ketones.
    03:29

Alkyne Hydrohalogenation

  • Double hydrohalogenation of alkynes.
    02:20
  • General properties of double addition reactions to alkynes.
    01:01

Alkyne Halogenation

  • Double halogenation of alkynes.
    02:15

Alkyne Hydration

  • Alkyne Hydration
    09:11

Tautomerization

  • Tautomerization Mechanisms
    05:11
  • Unusual Acidity of the Alpha Carbon
    01:51