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Chapter 19: Amines – Structure, Properties, and Reactions

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Naming Amines

  • Naming Primary Amines
    06:50
  • Primary Amines as Substituents
    02:58
  • Naming Secondary and Tertiary Amines
    01:57

Chirality

  • Drawing Mirror Images and Determining Chirality
    03:24
  • What is chirality?
    05:10
  • Drawing Mirror Images and Determining Chirality
    03:44

Cahn-Ingold-Prelog Nomenclature

  • R and S Naming- Step 4
    03:07
  • Why stereoisomers need their own naming system.
    01:48
  • Determining Priorities
    01:19

Amine Alkylation

  • General Reaction
    03:51
  • Propose a Synthesis
    03:46
  • Mechanism
    03:54

Introduction to Substitution

  • Predict the product
    05:55
  • Nucleophiles and Electrophiles can react in Bronsted-Lowry Reactions.
    05:01
  • Nucleophiles and Electrophiles can react in Substitution Reactions.
    01:47

Acylation of Aniline

  • Protection of Aniline Derivatives
    05:15
  • Synthesize the target molecule
    03:46

Hofmann Elimination

  • Provide the Major Product
    01:14
  • Mechanism
    06:45
  • General Reaction
    03:22

Acid and Base Definitions

  • Lewis vs. Bronsted-Lowry Definition
    07:46
  • The Bronsted-Lowry definition of acids and bases.
    00:54
  • Equilibrium constant and conjugates.
    02:11

pKa Values

  • Identifying pKa values
    07:45
  • The 12 pKa values you want to memorize (because they are important!).
    09:36

Acid Base Equilibrium

  • The 3 steps for determining the direction of acid and base equilibrium.
    05:11
  • Determining Acid/Base Equilibrium
    04:00
  • Determining Acid/Base Equilibrium
    02:34

Basicity of Aromatic Heterocycles

  • The Sp2 Rule
    02:54
  • Heterocycles - Which lone pairs react?
    02:04
  • Draw the acid/base reaction product
    03:55

NMR Spectroscopy

  • General NMR Features
    10:06

Infrared Spectroscopy

  • General Features of IR Spect
    16:04

Mass Spectrometry

  • Equipment and Theory
    10:48
  • How to Read a Mass Spectrum
    01:25

Reductive Amination

  • Reductive Amination
    07:12
  • Provide the Major Product
    03:07

Gabriel Synthesis

  • Mechanism
    05:42
  • General Reaction
    04:53