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Fundamentals of Organic Reaction Mechanisms: Structure, Bonding, and Molecular Orbitals

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Reaction Mechanism

  • How to tell if charged molecules will react as nucleophiles or electrophiles.
    02:39
  • Nucleophile or Electrophile
    01:49
  • How to tell if uncharged molecules will react as nucleophiles or electrophiles.
    02:48

Molecular Orbital Theory

  • Sigma bond vs. pi bond, which is stronger?
    03:25
  • What’s the difference between sigma and pi bonds?
    02:19
  • What’s the difference between atomic and molecular orbitals?
    11:25

Formal Charges

  • Calculate the formal charges of ALL atoms.
    02:21
  • Calculating formal and net charge.
    01:34

Resonance Structures

  • How to draw a resonance hybrid.
    03:24
  • The rules you need for resonance:
    03:34
  • How to determine which structure is most stable.
    01:32

Hybridization

  • How carbon creates 4 partially-filled orbitals.
    02:53
  • Bond sites, hybridization, and intermediate orbitals
    04:58
  • Introduction to the reactive intermediates.
    02:47

Molecular Orbital Theory

  • Review of Atomic Orbitals
    16:
  • Review of Molecular Orbitals
    08:41

Drawing Molecular Orbitals

  • MO of 1,3-butadiene
    08:38
  • The 7 Rules of Drawing Molecular Orbitals
    03:44

HOMO LUMO

  • HOMO vs. LUMO
    02:35