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Isomerism and Stereochemistry in Organic Chemistry

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Functional Groups

  • Assigning Degrees to Alkyl Halides
    01:30
  • Why we need functional groups.
    01:49
  • The difference between aldehydes and ketones.
    03:08

Constitutional Isomers

  • Isomeric Relationships
    03:28
  • Using the flowchart to determine isometric relationships.
    05:02
  • Isomeric Relationships
    02:56

Chirality

  • Drawing Mirror Images and Determining Chirality
    03:24
  • What is chirality?
    05:10
  • Drawing Mirror Images and Determining Chirality
    03:44

Chirality Test 1 - Internal Line of Symmetry

  • Determining Chirality with Plane of Symmetry
    00:25
  • Determining Chirality with Plane of Symmetry
    01:10
  • How and when to use the internal line of symmetry test.
    01:25

Chirality Test 2 - Stereocenters

  • Determining Chirality using Stereocenter
    02:25
  • Determining Chirality using Stereocenter
    00:36
  • The difference between chiral and trigonal centers.
    02:38

Cahn-Ingold-Prelog Nomenclature

  • R and S Naming- Step 4
    03:07
  • Why stereoisomers need their own naming system.
    01:48
  • Determining Priorities
    01:19

Types of Stereoisomers

  • Determine total number of stereoisomers
    00:49
  • How to predict the total number of stereoisomers.
    01:03
  • Draw stereoisomers and determine relationship
    07:41

Meso Compounds

  • Defining meso compounds.
    01:40
  • The 3 rules of meso compounds.
    04:10
  • Which of the following molecules are meso?
    03:44

Chirality Test 3 - Disubstituted Cycloalkanes Shortcuts

  • Is the following disubstituted cyclobutane chiral?
    00:35
  • Three types of disubstituted cycloalkanes
    03:52
  • Is the following disubstituted cyclopropane chiral?
    00:22

Isometric Relationships

  • Same atoms, same connectivity, 1 chiral center.
    01:40
  • Same atoms, same connectivity, 1 or more trigonal centers.
    02:05
  • Different atoms or different connectivity.
    01:41