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Organic Chemistry: Chemical Reactions, Stereochemistry, and Nucleophilic Substitution

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Radical Reaction

  • What are Radical Initiators?
    03:49
  • Heterolytic vs. Homolytic Bond Cleavage .
    04:39

Free Radical Halogenation

  • The one reaction that alkanes will actually undergo.
    02:05
  • Explaining the following problem.
    00:34
  • Show the entire chain reaction mechanism.
    04:08

Radical Stability

  • The radical stability trend.
    03:43
  • Determine which of the following radicals is the most stable.
    03:25

Radical Selectivity

  • Predict the Product.
    00:48
  • Predict the Product.
    01:02
  • Using the Hammond Postulate to describe radical chlorination.
    03:03

Energy Diagram

  • Favorability and rate of Free Energy Diagrams
    01:14
  • Favorability and rate of Free Energy Diagrams
    00:34
  • Favorability and rate of Free Energy Diagrams
    02:18

Gibbs Free Energy

  • Intermediates vs. Transition States
    06:55
  • Breaking down the different terms of the Gibbs Free Energy equation.
    05:02

Enthalpy

  • How to calculate enthalpy using bond dissociation energies.
    04:09
  • Calculating Enthalpies
    04:38

Entropy

  • 3 ways to increase entropy.
    07:11
  • Explaining what entropy is.
    02:46

Hammond Postulate

  • Defining the Hammond Postulate.
    01:30
  • Bromination explains the Hammond Postulate.
    02:58
  • Chlorination explains the Hammond Postulate.
    05:23

Chirality

  • Drawing Mirror Images and Determining Chirality
    03:24
  • What is chirality?
    05:10
  • Drawing Mirror Images and Determining Chirality
    03:44

Cahn-Ingold-Prelog Nomenclature

  • R and S Naming- Step 4
    03:07
  • Why stereoisomers need their own naming system.
    01:48
  • Determining Priorities
    01:19

Introduction to Substitution

  • Predict the product
    05:55
  • Nucleophiles and Electrophiles can react in Bronsted-Lowry Reactions.
    05:01
  • Nucleophiles and Electrophiles can react in Substitution Reactions.
    01:47

Naming Alkyl Halides

  • How to name alkyl halides
    01:52
  • Name the following alkyl halide
    01:58
  • Name the following alkyl halide
    03:53