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Organic Chemistry Exam 3 Study Guide: Reaction Mechanisms, Alkene Additions, and NMR Spectroscopy
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Overview of Chemical Reactions
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Recognizing Substitution Reactions.
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Recognizing Acid-Base Reactions.
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Recognizing Elimination Reactions.
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Reaction Mechanism
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How to tell if charged molecules will react as nucleophiles or electrophiles.
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Nucleophile or Electrophile
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How to tell if uncharged molecules will react as nucleophiles or electrophiles.
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NMR Spectroscopy
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General NMR Features
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1H NMR:Number of Signals
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General Assumption for 1H NMR Signals
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Identifying Proton Signals
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Identifying Proton Signals
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Carbon NMR
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13C NMR General Features
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1H and 13C Joint Problem
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Identifying 13C Signals
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Formal Charges
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Calculate the formal charges of ALL atoms.
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Calculating formal and net charge.
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Acid and Base Definitions
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Lewis vs. Bronsted-Lowry Definition
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The Bronsted-Lowry definition of acids and bases.
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Equilibrium constant and conjugates.
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pKa Values
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Identifying pKa values
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The 12 pKa values you want to memorize (because they are important!).
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Acid Base Equilibrium
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The 3 steps for determining the direction of acid and base equilibrium.
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Determining Acid/Base Equilibrium
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Determining Acid/Base Equilibrium
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Functional Groups
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Assigning Degrees to Alkyl Halides
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Why we need functional groups.
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The difference between aldehydes and ketones.
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