Question 1

Which of the following statements best describes resonance in organic molecules?

Accepted Answer

Resonance forms are different Lewis structures that can be interconverted by moving electrons only, not atoms.

Question 2

Which criterion is considered MOST important when determining the major contributor among resonance forms?

Accepted Answer

The structure in which all atoms have a complete octet of electrons.

Question 3

Given the resonance forms of the acetate ion, why is the negative charge delocalized over both oxygen atoms?

Accepted Answer

Because both oxygens are equally electronegative and can share the negative charge through resonance.

Question 4

Which of the following resonance forms is the major contributor for the cyanate ion ($$\mathrm{NCO}^-$$)?

Accepted Answer

The form with the negative charge on oxygen.

Question 5

In the resonance forms of $$\mathrm{CH_3OCH_2^+}$$, why is the structure with octets on all atoms considered the major contributor?

Accepted Answer

Because all atoms have a complete octet and there is an additional bond.

Question 6

Which of the following best explains why the resonance hybrid is more stable than any individual resonance form?

Accepted Answer

Because the hybrid averages the electron density, reducing charge separation and increasing stability.

Question 7

Consider the resonance forms of formate ion ($$\mathrm{$$HCO_2$$^-}). $$Which statement is correct?

Accepted Answer

Both resonance forms have the negative charge on oxygen, and the true structure is a hybrid.

Question 8

Which of the following is NOT a criterion for evaluating the stability of resonance forms?

Accepted Answer

Having the positive charge on the least electronegative atom.

Question 9

In the resonance forms of $$\mathrm{CH_3ON=O}$$, why is the form with opposite charges on adjacent atoms more stable?

Accepted Answer

Because opposite charges on adjacent atoms minimize the energy due to electrostatic attraction.

Question 10

Which of the following molecules is best represented by a resonance hybrid rather than a single Lewis structure?

Accepted Answer

Acetate ion ($$\mathrm{CH_3CO_2^-})$$

Question 11

A student draws two resonance forms for a molecule. Both forms obey the octet rule, but one has the negative charge on oxygen and the other on carbon. Which is the major contributor?

Accepted Answer

The form with the negative charge on oxygen.

Question 12

Which of the following best describes the bond order of the carbon-oxygen bonds in the acetate ion ($$\mathrm{CH_3CO_2^-}$$)?

Accepted Answer

Each C–O bond is intermediate between a single and a double bond due to resonance.

Question 13

Which of the following is a common mistake when drawing resonance forms?

Accepted Answer

Moving atoms instead of electrons.

Question 14

In a resonance structure, why is it preferable to have as little charge separation as possible?

Accepted Answer

Because charge separation increases the molecule's energy and decreases stability.

Question 15

Which of the following is true about the resonance hybrid of a molecule?

Accepted Answer

It represents the average of all possible resonance forms.

Question 16

A molecule has two resonance forms: one with a negative charge on nitrogen and one with a negative charge on oxygen. Which is the major contributor?

Accepted Answer

The form with the negative charge on oxygen.

Question 17

Which of the following best explains why the acetate ion is more stable than the acetic acid molecule?

Accepted Answer

Because the negative charge in acetate is delocalized over two oxygen atoms, increasing stability.

Question 18

Which of the following is NOT a valid resonance form for the nitrate ion ($$\mathrm{NO_3$^-}$$)?

Accepted Answer

A form with the negative charge on nitrogen.

Question 19

Which of the following real-world phenomena is explained by resonance stabilization?

Accepted Answer

The color and stability of the firefly's luciferin molecule.

Resonance in Organic Chemistry: Principles, Contributors, and Applications

스터디 가이드 - 연습 문제

학습 가이드 - 플래시카드