Predict the product of the following reductions.
(d)

검증된 단계별 안내

Identify the functional groups present in the starting material. The compound contains an ester group, which is susceptible to reduction.

Recognize the reducing agent used in the reaction. Lithium aluminum hydride (LiAlH4) is a strong reducing agent capable of reducing esters to primary alcohols.

Understand the mechanism of reduction by LiAlH4. The hydride ion (H-) from LiAlH4 attacks the carbonyl carbon of the ester, leading to the formation of an alkoxide intermediate.

The alkoxide intermediate is then protonated during the aqueous workup (H3O+ quench) to form the corresponding alcohol.

Predict the product by considering the reduction of the ester group to a primary alcohol. The tert-butyl group and the cyclohexane ring remain unchanged in the product.

비슷한 문제에 대한 검증된 영상 답변:

이 영상 해법은 위 문제에 도움이 된다고 튜터들이 추천한 것입니다.

주요 개념

질문에 올바르게 답하기 위해 반드시 이해해야 하는 핵심 개념들은 다음과 같습니다.

Reduction Reactions

Reduction reactions in organic chemistry involve the gain of electrons or hydrogen, or the loss of oxygen by a molecule. These reactions typically convert carbonyl compounds, alkenes, or alkynes into alcohols or alkanes. Understanding the type of functional groups present in the substrate is crucial for predicting the outcome of the reduction.

Common Reducing Agents

Common reducing agents include lithium aluminum hydride (LiAlH4), sodium borohydride (NaBH4), and hydrogen gas (H2) in the presence of a catalyst. Each reducing agent has specific reactivity and selectivity, influencing which functional groups can be reduced and to what extent. Knowing the properties of these agents helps in predicting the products of reduction reactions.

Stereochemistry of Reduction Products

The stereochemistry of reduction products is important, as reductions can lead to the formation of chiral centers. Depending on the substrate and the reducing agent used, the reaction may yield different stereoisomers. Understanding how the spatial arrangement of atoms affects the product is essential for predicting the outcome of reductions, especially in complex organic molecules.

Predict the product of the following reductions.(d)